2,4-Dinitrophenol 2,4-二硝基酚(易制爆)

CAS 51-28-5 MFCD00007115

化学结构图

51-28-5
SMILES: O=[N+]([O-])c1ccc(O)c([N+](=O)[O-])c1

化学属性

Mol. FormulaC6H4N2O5
Mol. Weight184.12
Melting Point108-112 °C(lit.)
TSCAYes
Vapor Density6.35 (vs air)
Solubility0.6 G/100 ML (18 ºC)
Flash Point11 °C
Density0.7915

别名和识别编码

Chemical Name2,4-Dinitrophenol
Synonym Chemox pe 2.4-二硝基酚 2,4-DINITROPHENOL Chemox PE 2'4-Dinitrophenol 2,4-dinitro-pheno 2,4-DNP Aldifen ALPHA-DINITROPHENOL 2,4-DINITROPHENOL 2.4-二硝基苯酚;2,4-二硝基酚;α-二硝基酚 2,4-二硝苯酚 Fenoxyl carbon N A-Dinitrophenol camellomosquitocoils Solfo Black BB Phenol, alpha-dinitro- alpha-Dinitrophenol 1-hydroxy-2,4-dinitrobenzene 2,4-Dnp fenoxyl carbon N 1-Hydroxy-2,4-dinitrobenzol 2,4-二硝基酚 2,4-二硝基酚 085-01 [4.1] alpha-dinitro-pheno Tertrosulphur PBR Solfo Black B Fenoxyl Nitro kleenup Maroxol-50 2,4-Dinitrophenol fenosylcarbonn α-二硝基酚 caswellno.392 2.4-二硝基苯酚 Tertrosulphur Black PB EK 102 Solfo Black SB Phenol, a-dinitro- phenol, 2,4-dinitro- 1-Hydroxy-2,4-dinitrobenzene 2,4-dinitro-phenol Nitrophene benzene, 1-hydrox-2,4-dinitro- Dinitrofenolo 2，4-二硝基苯酚 Dinofan α-二硝基酚 Solfo Black 2B Supra Phenol, α-dinitro- Fenoxyl Carbon N Solfo Black G Dinitrophenols Dinitra α-dinitrophenol 2,4-Dinitrofenol 2,4-二硝基苯酚, 97%, STAB. WITH 30-35% WATER X 32 cobrasalts(impregnasalts) 2,4-dinitrophenol DNP RCRA waste number P048 dinitro-2,4phenol NSC 1532
CAS Number51-28-5
PubChem Substance ID1493
EC Number200-087-7
Beilstein Registry Number1246142
MDL NumberMFCD00007115
Merck Number14,3280
Chemical Name Translation2,4-二硝基酚(易制爆)
Wiswesser Line NotationWNR BQ ENW
InChIInChI=1S/C6H4N2O5/c9-6-2-1-4(7(10)11)3-5(6)8(12)13/h1-3,9H
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分类

  • Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, D, DID - DIN, Environmental Standards, Others, Pesticides & Metabolites, Pesticides Standards

相关文献及参考

  • Merck 14 ,3280
  • Beil. 6 ,IV,1369
  • Aldrich MSDS 1 , 816:C / Corp MSDS 1 (1), 1439:D / FT-IR 1 (1), 1370:C / FT-IR 2 (2), 2314:B / FT-NMR 1 (2), 750:C / IR-Spectra (3), 828:F / IR-Spectra (2), 726:D / NMR-Reference 2 (1), 1174:C / RegBook 1 (1), 1587:J / Sax 6 , 1215 / Sigma FT-IR 1 (2), 517:A / Structure Index 1 , 247:B:7
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13
  • Acid-base indicator; approx. pH 2.8-4.4.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Hazard Codes T,N T,N,Xi,F T;N
Precautionary statements
  • P301+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Signal word Danger
RTECSSL2800000
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S37 Wear suitable gloves 戴适当手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number 1320 UN 1320 4.1/PG 1 UN1320
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R33 Danger of cumulative effects 有累积作用的危险
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
  • R11 Highly flammable 非常易燃
  • R52/53
  • R1 Explosive when dry 干燥时易爆
Packing GroupI
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Class4.1
Storage condition 2-8°C
Restrict {} 剧毒化学品 易制爆
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 36 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
   Cardiac - change in rate
   Nutritional and Gross Metabolic - body temperature increase
REFERENCE :
   JAMAAP JAMA, Journal of the American Medical Association.  (AMA, 535 N.
   Dearborn St., Chicago, IL 60610)  V.1-    1883-  Volume(issue)/page/year:
   101,1333,1933

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 72 mg/kg
TOXIC EFFECTS :
   Behavioral - altered sleep time (including change in righting reflex)
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   6,232,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 26 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(iss

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 49,187,1933

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 7 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 243,213,1990

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 10 gm/kg
REFERENCE :
   IJMRAQ Indian Journal of Medical Research.  (Indian Council of Medical
   Research, Ansari Nagar, New Delhi 110 029, India)  V.1-    1913-
   Volume(issue)/page/year: 59,1442,1971

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 100 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 368,59,1996

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 200 ppm/3H
REFERENCE :
   AMNTA4 American Naturalist.  (Univ. of Chicago Press, Journals Div., POB
   37005, Chicago, IL 60637) V.1-    1867-  Volume(issue)/page/year:
   85,119,1951

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Fish - not otherwise specified Cells - not otherwise
                          specified
DOSE/DURATION           : 100 umol/L
REFERENCE :
   AEEXAH Acta Embryologiae Experimentalis.  (Industria Grafica Nazionale,
   Palermo, Italy) V.1-3, 1969-79.  Volume(issue)/page/year: (3),279,1972

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2040 mg/kg
SEX/DURATION            : female 8 day(s) pre-mating  - 21 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - stillbirth
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
REFERENCE :
   PSEBAA Proceedings of the Society for Experimental Biology and Medicine.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1903/04-
   Volume(issue)/page/year: 32,678,1935

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 40800 ug/kg
SEX/DURATION            : female 10-12 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 11,31,1973

其他信息

  • 方法一:由2,4-二硝基氯苯在碱溶液中水解而得。将1400L水加到水解锅中，搅拌加热至60℃，将750kg已熔化的2,4-二硝基氯苯加入锅内。继续升温到90℃，于1.5h内逐渐加入780L30%的氢氧化钠溶液。加料中温度上升，控制温度不超过102-104℃，保温30min。冷却，过滤析出的钠盐。用水溶解，酸化至pH为1，即析出2,4-二硝基酚的黄色结晶。另一种制备方法是由苯酚低温硝化而得。将67%的硫酸、53%的硝酸和苯酚在30℃以下混合均匀，然后，搅拌下加热至90℃，混合物开始激烈反应，并放出氧化氮，控制反应速度，减少反应物损失。反应缓和后再加热30min，冷却，过滤，水洗即得产品。精制可采用酸碱法或用乙醇重结晶。
  • 爆炸物危险特性:与氧化剂混合可爆
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • 用途二:主要用于硫化染料生产，如硫化黑BN、BRN、2BRN等。也用于生产苦味酸和显影剂等。分析化学中用作酸碱指示剂，变色范围是pH=2.8（无色）-4.4（黄色）；还可用于检测钾、铵、镁等。
  • 敏感性:Light Sensitive
  • 毒性分级:剧毒
  • 刺激数据:皮肤- 兔子 300 毫克/ 4周 轻度
  • 用途一:用于制造染料、苦味酸和显像剂等
  • Alfa Aesar:2,4-二硝基苯酚,97%,stab.with30-35%water 2,4-Dinitrophenol, 97%, stab. with 30-35% water(51-28-5)
  • 外观性质:浅黄色结晶或粉末。
  • 急性毒性:口服- 大鼠 LD50: 30 毫克/ 公斤; 口服- 小鼠 LD50: 45 毫克/ 公斤
  • 类别:易燃固体
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
  • 酚类单一化合物标准液
  • 灭火剂:水、干砂、二氧化碳、泡沫、1211灭火剂
  • 蒸气密度:6.35 (vs air)
  • Sigma Aldrich:51-28-5(sigmaaldrich)
  • 2,4-二硝基酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80056556 2，4-二硝基酚（剧毒）（易制爆） 100g 160元
  • 图谱信息:2,4-二硝基酚(51-28-5)红外图谱(IR3) 2,4-二硝基酚(51-28-5)核磁图( 13 CNMR) 2,4-二硝基酚(51-28-5)红外图谱(IR2) 2,4-二硝基酚(51-28-5)Raman光谱 2,4-二硝基酚(51-28-5)红外图谱(IR1) 2,4-二硝基酚(51-28-5)质谱(MS)
  • 上游原料:2,4-二硝基氯苯 --> 一氧化氮
  • MSDS 信息:2,4-二硝基苯酚(51-28-5).msds
  • MOL 文件:51-28-5.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DID - DIN - D

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