N-Methyl-4-Nitroaniline N-甲基-4-硝基苯胺

CAS 100-15-2 MFCD00007305

化学结构图

100-15-2
SMILES: CNc1ccc([N+](=O)[O-])cc1

化学属性

Mol. FormulaC7H8N2O2
Mol. Weight152
Melting Point149-151
Density1.422
TSCAYes
Vapor Density5.25 (vs air)
Solubility<0.1 G/100 ML AT 19 ºC
Appearance 棕黄色带紫光的棱状结晶。熔点152℃。易溶于丙酮、苯，微溶于乙醇，不溶于水。

别名和识别编码

Chemical NameN-Methyl-4-Nitroaniline
Beilstein Registry Number637920
PubChem Substance ID7483
CAS Number100-15-2
EC Number202-823-2
MDL NumberMFCD00007305
Reaxys-RN637920
Synonym p-(Methylamino)nitrobenzene N-甲基-4-硝基苯胺(0403限出口,需提供最终用户说明以申请出口许可证) N-METHYL-4-NITRO ANILIN N-Methyl-N-(4-nitrophenyl)amine Aniline, N-methyl-p-nitro- (p-nitrophenyl)-methylamin Methyl(4-nitrophenyl)amine 4-Nitro-N-methylaniline N-methyl-4-nitro-Benzenamine N-甲基对硝基苯胺 N-Methyl-4-nitroaniline N-METHYL-4-NITROANILINE N-Methyl-4-nitrobenzenamine N-Methyl-p-nitroaniline N-methyl-4-nitro-aniline p-(Methylamino)nitrobenzene N-Methyl-p-nitroanilin n-methyl-4-nitro-benzenamin P-NITRO-N-METHYLANILINE 4-Methylaminonitrobenzene p-Nitro-N-methylaniline 硝基苯胺 N-Methyl-p-nitraniline 4-(Methylamino)nitrobenzene Aniline, N-methyl-p-nitro- 4-Methylaminonitrobenzol N1-methyl-4-nitroaniline N-Monomethyl-p-nitroaniline 4-nitro-n-methylaniline 1-METHYLAMINO-4-NITROBENZENE N-Methyl-4-nitroaniline ,99% N-METHYL-P-NITROANILINE 4-METHYLAMINONITROBENZENE Nitronaniline N-Methyl-p-nitraniline N-甲基-4-硝基苯胺 N-Monomethyl-p-nitroaniline Benzenamine, N-methyl-4-nitro- N-甲基-对-硝基苯胺 Benzenamine,N-methyl-4-nitro-
Chemical Name TranslationN-甲基-4-硝基苯胺
InChIKeyXIFJZJPMHNUGRA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00224384
InChIInChI=1S/C7H8N2O2/c1-8-6-2-4-7(5-3-6)9(10)11/h2-5,8H,1H3
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分类

  • Amines, Building Blocks, C7, Chemical Synthesis, Materials Science, NLO Chromophores and Intermediates, Nitrogen Compounds, Non-Linear Optical (NLO) Materials, Organic Building Blocks, Organic and Printed Electronics, Photonic and Optical Materials
  • {SNA} Amines, Building Blocks, C7, Chemical
  • {SNA} Amines, Building Blocks, C7, Chemical Synthesis, Materials Science, NLO Chromophores and Intermediates, Nitrogen Compounds, Non-Linear Optical (NLO) Materials, Organic Building Blocks, Organic and Printed Electronics, Photonic and Optical Materials

相关文献及参考

  • Beil. 12 ,IV,1616
  • Corp MSDS 1 (2), 2387:D / FT-NMR 1 (2), 702:B / RegBook 1 (1), 1563:A / Structure Index 1 , 243:D:5 / Vapor Phase 3 , 1193:D
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P312+P361+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P304+P340+P311
  • P301+P310
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
WGK Germany3
GHS Symbol
Signal word
Hazard statements
  • H301+H311+H331
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Hazard Codes T,Xi T
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R51/53
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number
Packing GroupIII
Hazard Class6.1

其他信息

  • 用途二:用于有机合成，染料中间体。
  • 图谱信息:N-甲基对硝基苯胺(100-15-2)红外图谱(IR2) N-甲基对硝基苯胺(100-15-2)质谱(MS) N-甲基对硝基苯胺(100-15-2)核磁图( 13 CNMR) N-甲基对硝基苯胺(100-15-2)核磁图( 1 HNMR) N-甲基对硝基苯胺(100-15-2)红外图谱(IR1)
  • Sigma Aldrich:100-15-2(sigmaaldrich)
  • Hazard Note:Highly Toxic/Irritant
  • 用途一:用作染料中间体
  • 蒸气密度:5.25 (vs air)
  • 下游产品:六硝基癸啉 --> 2-氨基-5-硝基苯酚 --> 2-氨基-5-硝基二苯甲酮 --> 直接黑 FF --> 对硝基苯胂酸 --> 铬变素2B --> 偶氧紫 --> 分散橙3 C.I.11005
  • N-甲基对硝基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1011 N-甲基-4-硝基苯胺 N-Methyl-4-nitroaniline 25G 200元 2014/06/02 M1011 N-甲基-4-硝基苯胺 N-Methyl-4-nitroaniline 500G 2000元 2010/06/21 123570500 N-甲基对硝基苯胺 N-Methyl-4-nitroaniline 97% 50 GR 1174元
  • MOL 文件:100-15-2.mol
  • 方法一:以对硝乙酰苯胺、碘甲烷和乙醇为原料制得。将丙酮、对硝基乙酰苯胺、氢氧化钾混合后加热回流，并滴加碘甲烷的丙酮溶液，加毕，继续回流4h。放置过夜，回收丙酮后析出结晶，放冷洗去碱性，以乙醇洗涤而得N-甲基对硝基乙酰苯胺。然后将其与乙醇、盐酸混合，加热回流8h，回收乙酸乙酯和乙醇，再用水中冲稀，洗去酸性，干燥得到粗品。用丙酮溶解粗品，过滤，回收丙酮析出结晶即为成品。
  • Alfa Aesar:N-甲基-对硝基苯胺,97% N-Methyl-4-nitroaniline, 97%(100-15-2)
  • MSDS 信息:4-Nitro-N-methylaniline(100-15-2).msds
  • Acros Organics:N-甲基-对-硝基苯胺 N-Methyl-4-nitroaniline, 97%(100-15-2)
  • 上游原料:碘甲烷 --> 对硝基乙酰苯胺
  • 检测方法:HPLC,NMR

系列性分类

  1. C7 - Amines
  1. C10 to C11 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C2 to C6
  1. Materials Science 材料科学
  2. Organic Nonlinear Optical Materials