2-(Bromomethyl)-4-Nitrophenol 2-羟基-5-硝基苄溴

CAS 772-33-8 MFCD00007340

化学结构图

772-33-8
SMILES: [O-][N+](=O)C1C=CC(O)=C(CBr)C=1

化学属性

Mol. FormulaC7H6BrNO3
Mol. Weight232.03 g/mol
Melting Point144-149
Density1.422
TSCAYes

别名和识别编码

Chemical Name2-(Bromomethyl)-4-Nitrophenol
Synonym α-溴-4-硝基邻甲酚 α-溴-4-硝基邻甲酚 2-溴甲基-4-硝基苯酚 Koshland I Koshland 试剂 I -Bromo-4-nitro-o-cresol, 2-Bromomethyl-4-nitrophenol,Koshland 2-(Bromomethyl)-4-nitrophenol 2-HYDROXY-5-NITROBENZYL BROMIDE 2-Hydroxy-5-nitrobenzyl Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number1868798
PubChem Substance ID13044
CAS Number772-33-8
EC Number212-248-9
MDL NumberMFCD00007340
Reaxys-RN1868798
Chemical Name Translation2-羟基-5-硝基苄溴
InChIKeyKFDPCYZHENQOBV-UHFFFAOYSA-N
LabNetwork Molecule IDLN01357956
InChIInChI=1S/C7H6BrNO3/c8-4-5-3-6(9(11)12)1-2-7(5)10/h1-3,10H,4H2
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分类

  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • 1. Aldrichimica Acta 18 , 78, (1985)
  • Beil. 6 ,H,367
  • Aldrich MSDS 1 , 1071:C / Corp MSDS 1 (1), 1946:C / FT-IR 1 (1), 1361:C / FT-IR 2 (2), 2298:A / FT-NMR 1 (2), 733:A / NMR-Reference 2 (1), 1163:D / RegBook 1 (1), 1579:B / Sigma FT-IR 1 (2), 639:B / Structure Index 1 , 246:A:2

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P303+P361+P353
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P330+P331+P310
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P305+P351+P338+P310
WGK Germany3
GHS Symbol
Signal word
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302+H312+H332
Hazard Codes
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
Risk Statements
  • R34 Causes burns 会导致灼伤
UN Number UN 3261 8/PG 2 1759
Packing GroupII
Hazard Class8
Storage condition 2-8°C

其他信息

  • ALPHA-溴-4-硝基-O-甲酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0601 2-羟基-5-硝基溴苄 2-Hydroxy-5-nitrobenzyl Bromide 5G 526元 2010/06/21 388520050 ALPHA-溴-4-硝基-O-甲酚 alpha-Bromo-4-nitro-o-cresol 95% 5 GR 352元 2010/06/21 388520250 ALPHA-溴-4-硝基-O-甲酚 alpha-Bromo-4-nitro-o-cresol 95% 25 GR 1391元
  • 图谱信息:ALPHA-溴-4-硝基-O-甲酚(772-33-8)质谱(MS) ALPHA-溴-4-硝基-O-甲酚(772-33-8)红外图谱(IR2) ALPHA-溴-4-硝基-O-甲酚(772-33-8)红外图谱(IR1)
  • 上游原料:硫酸 --> 苯 --> 氢溴酸 --> 三溴化磷 --> 4-硝基苯酚 --> 二甲醇缩甲醛
  • 存储注意事项:湿度敏感
  • 检测方法:HPLC
  • TCI Shanghai:2-羟基-5-硝基苄溴 2-Hydroxy-5-nitrobenzyl Bromide,>;95.0%(T)(772-33-8)
  • MOL 文件:772-33-8.mol
  • Acros Organics:2-羟基-5-硝基苄溴 alpha-Bromo-4-nitro-o-cresol, 95%(772-33-8)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Protein Structural Analysis - Proteomics
  4. Protein Modification - Protein Structural Analysis
  5. Specific Amino Acid Modification - Protein Modification
  6. Reagents for tryptophan modification - Specific Amino Acid Modification
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Protein Structural Analysis
  5. Protein Modification
  6. Specific Amino Acid Modification
  7. Reagents for lysine modification

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