3-(Methylthio)aniline 3-氨基茴香硫醚

CAS 1783-81-9 MFCD00007793

化学结构图

1783-81-9
SMILES: CSc1cccc(N)c1

化学属性

Mol. FormulaC7H9NS
Mol. Weight139.22
Boiling Point292.6°C at 760 mmHg
TSCAT
Density1.13
Refractive indexn20/D 1.637(lit.)
Flash Point113.9°C
pH:A
Melting PointN/A

别名和识别编码

Chemical Name3-(Methylthio)aniline
CAS Number1783-81-9
Alfabeta NameMETHYLTHIOANILINE 3()-
MDL NumberMFCD00007793
Synonym 3-(Methylthio)aniline {LY} 3-(Methylthio)aniline {} {LY} 3-(Methylthio)aniline {} {} {LY} 3-(Methylthio)aniline {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Methylthio)aniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number217-232-5
Beilstein Registry Number2078599
PubChem Substance ID15693
Reaxys-RN2078599
Chemical Name Translation3-氨基茴香硫醚
InChIKeyKCHLDNLIJVSRPK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00114658
InChIInChI=1S/C7H9NS/c1-9-7-4-2-3-6(8)5-7/h2-5H,8H2,1H3
Canonical SMILESNC1=CC=CC(SC)=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; sulfide; 1fragment

相关文献及参考

  • Short: II/27B
  • Short: III/35D2
  • Beilstein:13(4)1007

安全信息

Warnings IRRITANT, STENCH
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSBY6301000
Packing GroupIII
UN Number 2810 UN 2810 6.1/PG 3 UN2810
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 Xi
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 急性毒性:口服-鹌鹑 LD50: 750 毫克/公斤; 口服-鸟LD50: 750 毫克/公斤
  • Acros Organics:3-(Methylmercapto)aniline, 97%(1783-81-9)
  • MOL 文件:1783-81-9.mol
  • 储运特性:库房通风低温干燥
  • F:2-8-13
  • 毒性分级:中毒
  • Alfa Aesar:3-(甲基硫代)苯胺,97% 3-(Methylthio)aniline, 97%(1783-81-9)
  • TSCA:T
  • TCI Shanghai:3-甲硫基苯胺 3-(Methylthio)aniline,>;98.0%(GC)(T)(1783-81-9)
  • 灭火剂:干粉、泡沫、砂土, 二氧化碳, 雾状水
  • 用途一:用作药物中间体
  • 3-氨基茴香硫醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1673 3-(甲硫基)苯胺 3-(Methylthio)aniline 25G 589元 2010/06/21 163191000 3-氨基茴香硫醚 3-(Methylthio)aniline 97% 100 GR 13190元 2010/06/21 163190100 3-氨基茴香硫醚 3-(Methylthio)aniline 97% 10 GR 2476元
  • Sigma Aldrich:1783-81-9(sigmaaldrich)
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和硫氧化物烟雾
  • 图谱信息:3-氨基茴香硫醚(1783-81-9)核磁图( 13 CNMR) 3-氨基茴香硫醚(1783-81-9)质谱(MS) 3-氨基茴香硫醚(1783-81-9)红外图谱(IR1)
  • 检测方法:GC,NMR
  • Hazard Note:Harmful
  • 类别:有毒物品

系列性分类


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