Hexamethylditin 六甲基二锡

CAS 661-69-8 MFCD00008277

化学结构图

661-69-8
SMILES: C[Sn](C)C.C[Sn](C)C

化学属性

Mol. FormulaC6H18Sn2
Mol. Weight327.63
Boiling Point182°C(lit.)
Density1.58 g/mL at 20 °C(lit.)
Melting Point23-24 °C(lit.)
Refractive index1.5410
Flash Point61°C(lit.)
TSCANo
pH-:A
Danger-Level-
Redox-

别名和识别编码

Chemical NameHexamethylditin
Synonym Distannane, hexamethyl- HEXAMETHYLDISTANNANE HEXAMETHYLDITIN HEXAMETHYLDITIN(IV) Hexamethylditin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number661-69-8
PubChem Substance ID6327618
EC Number211-549-2
Beilstein Registry Number4(4)4346
MDL NumberMFCD00008277
Reaxys-RN3600327
Chemical Name Translation六甲基二锡
Wiswesser Line Notation1-SN-1&1&-SN-1&1&1
InChIKeyCCRMAATUKBYMPA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00001309
InChIInChI=1S/6CH3.2Sn/h6*1H3;;
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分类

  • Chemical Synthesis, Organoditins, Organometallic Reagents, Organotin
  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Chemical Synthesis, Organoditins, Organometallic Reagents, Organotin
  • {SNA} Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Organoditins, Organometallic Reagents, Organotin

相关文献及参考

  • 1. Tetrahedron Lett. 47 , 8973, (2006)
  • 2. Tetrahedron Lett. 47 , 8607, (2006)
  • Beil. 4 ,IV,4346
  • Fieser 6 ,273 / Fieser 13 ,142 / Fieser 17 ,143
  • Corp MSDS 1 (1), 1851:C / FT-IR 2 (3), 4477:C / FT-NMR 1 (3), 737:B / RegBook 1 (2), 3043:C / Sax 6 , 1521 / Structure Index 1 , 481:B:6 / Vapor Phase 3 , 1682:A
  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H300+H310+H330
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T+,N
RTECSWH8280000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P403+P233
  • P302+P352+P310+P361+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
UN Number 3146
Risk Statements
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R28 Very toxic if swallowed 吞咽极毒
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R50/53
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S27/28
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Storage condition Air Sensitive
Packing GroupII
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7690 ug/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - excitement
   Behavioral - ataxia
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555199

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 53800 ug/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555183

Restrict 剧毒

其他信息

  • F:10-23
  • 敏感性:Air Sensitive
  • Alfa Aesar:六甲基二锡,97% Hexamethylditin, 97%(661-69-8)
  • Acros Organics:六甲基二锡 Hexamethylditin, 99%(661-69-8)
  • 六甲基二锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 295850010 六甲基二锡 Hexamethylditin 99% 1 GR 412元 2010/06/21 295850250 六甲基二锡 Hexamethylditin 99% 25 GR 4830元 2010/06/21 295850050 六甲基二锡 Hexamethylditin 99% 5 GR 1248元
  • TSCA:No
  • MOL 文件:661-69-8.mol
  • Sigma Aldrich:661-69-8(sigmaaldrich)

系列性分类


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