Tri-m-tolylphosphine 三(3-甲苯基)膦

CAS 6224-63-1 MFCD00008532

化学结构图

6224-63-1
SMILES: Cc1cccc(P(c2cccc(C)c2)c2cccc(C)c2)c1

化学属性

Density1.422
TSCAYes
Mol. FormulaC21H21P
Mol. Weight304.37
Appearance white xtl.
Stabilityair sensitive
Melting Point97-99°C
Boiling Point423.1°C at 760 mmHg

别名和识别编码

Chemical NameTri-m-tolylphosphine
Synonym Tri-m-tolylphosphine {LY} Tri-m-tolylphosphine {} {LY} Tri-m-tolylphosphine {} {} {LY} Tri-m-tolylphosphine {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-m-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {
EC Number228-312-4
Beilstein Registry Number658863
PubChem Substance ID87576829
Chemical Name Translation三(3-甲苯基)膦
Reaxys-RN658863
InChIKeyLFNXCUNDYSYVJY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00224287
MDL NumberMFCD00008532
CAS Number6224-63-1
Canonical SMILESCC1=CC(P(C2=CC=CC(C)=C2)C3=CC=CC(C)=C3)=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Short: III/35C4
  • Short: EINECS

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under

其他信息

  • 检测方法:HPLC,NMR
  • F:10-23
  • 上游原料:乙醇 --> 盐酸 --> 乙酸乙酯 --> 四氢呋喃 --> 二氯甲烷 --> 石油醚 --> 镁 --> 三氯化磷 --> 3-溴甲基苯 --> 3,5-二甲基溴苯
  • 三间基苯基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1025 三(3-甲苯基)磷 Tris(3-methylphenyl)phosphine 5G 444元 2014/06/02 T1025 三(3-甲苯基)磷 Tris(3-methylphenyl)phosphine 25G 1340元 2010/06/21 317280050 三间基苯基膦 Tri-m-tolylphosphine 98% 5 GR 671元
  • Sigma Aldrich:6224-63-1(sigmaaldrich)
  • Acros Organics:Tri-m-tolylphosphine, 98%(6224-63-1)
  • TCI Shanghai:三(3-甲苯基)磷 Tris(3-methylphenyl)phosphine,>;98.0%(GC)(6224-63-1)
  • Alfa Aesar:三(间甲苯)膦,98+% Tri(m-tolyl)phosphine, 98+%(6224-63-1)
  • MOL 文件:6224-63-1.mol
  • 存储注意事项:空气敏感

系列性分类


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