Phenylmercury acetate 乙酸苯汞

CAS 62-38-4 MFCD00008691

化学结构图

62-38-4
SMILES: CC(=O)O[Hg]c1ccccc1

化学属性

Mol. FormulaC₈H₈HgO₂
Mol. Weight336.74
Melting PointNo Data Available
Density2.4
SolubilitySlightly soluble in water. Soluble in alcohol, benzene and glacial acetic acid
TSCAYes
Boiling Point
Flash Point-

别名和识别编码

Chemical NamePhenylmercury acetate
Synonym (ACETATO)PHENYL MERCURY (ACETOXYMERCURI)BENZENE (Acetato)phenylmercury Acetate phenylmercurique Acetoxy phenylmercury Acetoxyphenylmercury Algimycin 200 Antimucin WBR Antimucin WDR Be Buf Bufen 30 Contra Creme Dyanacide Fenylmerkuriacetat GALLOTOX(R) Hexasan (fungicide) Intercide PMA 18 LIQUIPHENE(R) Liquiphene Lorophyn MERCURI PHENYL ACET MERCURY PHENYL ACETATE Mercuriphenyl acet Mercuron Mercury, acetoxyphenyl- Merga Mersolite 8 NYLMERATE(R) Neantina Norforms Nuodex PMA 18 Nylmerate Octan fenylrtutnaty Ph
PubChem Substance ID16682730
EC Number200-532-5
Beilstein Registry Number3662930
MDL Number-
CAS Number62-38-4
Merck Number14,7300
Chemical Name Translation乙酸苯汞
Wiswesser Line Notation1VO-HG-R
LabNetwork Molecule IDLN00195892
InChIInChI=1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1
Canonical SMILES-
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分类

  • {SNA} Chemical Synthesis, Organomercury, Organometallic Reagents

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSOV6475000
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupII
UN Number UN1674 UN 1674 6.1/PG 2
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R25 Toxic if swallowed 吞咽有毒
  • R48/24/25
  • R50/53
Hazard Codes T,N
Hazard Class6.1
Storage condition 4 4°C APPROX 4°C
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 41 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 1,175,1992

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 17 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,295,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00921

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMSVAZ Acta Medica Scandinavica.  (Almqvist & Wiksell, POB 45150, S-10430
   Stockholm, Sweden) V.52-224, 1919-88.  Volume(issue)/page/year: 143,365,1952

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneou

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 200 ppm
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 36,218,1985

TYPE OF TEST            : Siste

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 2 mmol/L
REFERENCE :
   MJDHDW Mukogawa Joshi Daigaku Kiyo, Shokumotsu-hen.  Bulletin of Mukogawa
   Women's University, Food Science Series.  (Mukogawa Joshi Daigaku, 6-46,
   Ikebiraki-cho, Nishinomiya, Hyogo-ken, Japan) No.19-    1972-
   Volume(issue)/page/year: 28,F39,1980

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 77,109,1980

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 50 mmol/L
REFERENCE :
   MUREAV

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 1 umol/L
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   24,489,1975

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 10 umol/L
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   24,489,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 7500 ug/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - homeostasis
REFERENCE :
   LSBGAY Life Sciences, Part 2: Biochemistry, General and Molecular Biology.
   (New York, NY)  V.9-13, 1970-73.  For publisher information, see LIFSAK.
   Volume(issue)/page/year: 10,1341,1971

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravaginal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 110 ug/kg
SEX/DURATION            : female 7 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   ARINAU Annual Report of the Research Institute of Environmental Medicine,
   Nagoya University. (Nagoya, Japan)  V.1-25, 1951-80.
   Volume(issue)/page/year: 3,88,1956

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 15 mg/kg
SEX/DURATION            : female 6-10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - homeostasis
   Reproductive - Specific Developmental Abnormalities - other developmental
   abnormalities
REFERENCE :
   PARWAC Polskie Archiwum Weterynaryjne.  Polish Archives of Veterinary

其他信息

  • 灭火剂:水、泡沫、砂土、二氧化碳
  • 上游原料:氢氧化钠 --> 乙酸 --> 硝酸 --> 苯 --> 汞 --> 氧化汞(II), 黄
  • 外观性质:白色有光泽斜方晶体。
  • 图谱信息:苯基醋酸汞(62-38-4)红外图谱(IR1) 苯基醋酸汞(62-38-4)红外图谱(IR2) 苯基醋酸汞(62-38-4)Raman光谱 苯基醋酸汞(62-38-4)核磁图( 1 HNMR)
  • 刺激数据:眼- 兔子 0.005 毫克/ 24小时 重度
  • 急性毒性:口服- 大鼠 LD50: 41 毫克/ 公斤; 口服- 小鼠 LD50: 13.25 毫克/ 公斤
  • 毒性分级:剧毒
  • MSDS 信息:醋酸苯汞(62-38-4).msds
  • Acros Organics:苯基醋酸汞 Phenylmercuricacetate,98%(62-38-4)
  • TSCA:Yes
  • MOL 文件:62-38-4.mol
  • Sigma Aldrich:62-38-4(sigmaaldrich)
  • 类别:农药
  • 中毒症状:对皮肤、眼睛和呼吸道具有中度刺激作用,使皮肤产生过敏反应。
  • 用途二:作为农药主要用于拌种,可防治稻瘟病、白叶枯病、菌核病等多种病害,但目前已不作农药使用。在医药工业中用作避孕药的一种原料。
  • 用途一:用作医用杀菌剂、农用除莠剂、聚氨酯塑胶催化剂、防霉剂等
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 下游产品:J-686系列压敏胶粘剂 --> 硝酸苯汞
  • F:8
  • 职业标准:TLV-TWA 0.1 毫克 (汞)/ 立方米; STEL 0.15 毫克(汞)/ 立方米
  • 急救治疗:(1)用肥皂和水清洗皮肤,用大量水冲洗眼睛。如果仍感觉有刺激作用,则应进行专门的治疗(2)如果几小时前大量吞服,但并未出现大量呕吐,则必须洗胃,并采取措施减少胃肠吸收 (3)如患者伴有血压下降症状时,须采取对症治疗,无特效解毒药。
  • 苯基醋酸汞价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80100924 乙酸苯汞(剧毒) 25g 800元
  • 注意事项:对实验动物急性吸入毒性高和慢性毒性问题已撤消登记
  • 可燃性危险特性:遇明火、高热可燃; 受热产生有毒含汞化物烟雾
  • Alfa Aesar:苯基乙酸汞,98% Phenylmercury acetate, 98%(62-38-4)
  • 方法一:由苯、乙酸和氧化汞一步合成,经后处理制得。

系列性分类


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