ACETONE 丙酮(易制毒)

CAS 67-64-1 MFCD00008765

化学结构图

67-64-1
SMILES: CC(C)=O

化学属性

Mol. FormulaCH3COCH3
Mol. Weight58.08
Refractive indexn20/D 1.359(lit.)
Boiling Point56 °C/760 mmHg(lit.)
Density0.791 g/mL at 25 °C(lit.)
Melting Point-94 °C(lit.)
Flash Point-17°(1°F)
TSCAYes
Vapor Density2 (vs air)
Vapor Pressure184 mmHg ( 20 °C)
Solubility可溶

别名和识别编码

Chemical NameACETONE
CAS Number67-64-1
PubChem Substance ID57649966
EC Number200-662-2
Beilstein Registry Number635680
MDL NumberMFCD00008765
Merck Number14,66
Synonym 丙酮 PROPANONE 2-羟基丙羧酸 ACETONE 5000 丙酮纯度标准物质 阿西通,醋酮,二甲酮,2-丙酮 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, monohydrate 柠檬酸,一水 ACETONE: ALCOHOL DECOLORIZER SOLUTION ACETONE 300 ACETONUM EXTRAN(R) AP 22 柠檬酸(一水) DIMETHYL KETONE 柠檬酸 一水柠檬酸 PYROACETIC ETHER EXTRAN(R) AP22, ACID RINSE DETERGENT WITH CITRIC ACID 2-Propanone ACETONE D AKOS BBS-00004268 柠檬酸一水合物 FEMA 3326 柠檬酸单水合物, ACS, 99.0-102.0% 柠檬酸-水 EXTRAN AP 22 枸橼酸 柠檬酸单水合物, 99.5+% METHYL KETONE 柠檬酸 ACETONE EXTRAN(R) AP22 DETERGENT 一水柠檬酸 ACETONE, BUFFERED, TS ACETONE, BUFFERED 2-PROPANONE
Chemical Name Translation丙酮(易制毒)
InChIKeyYASYEJJMZJALEJ-UHFFFAOYSA-N
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Acetone, Amber Glass Bottles, Analytical Reagents, Analytical/Chromatography, CHROMASOLV for HPLC, Chromatography Reagents & Solvents, HPLC & UHPLC Solvents (CHROMASOLV), HPLC Grade Solvents (CHROMASOLV), HPLC/UHPLC Solvents (CHROMASOLV), Products, Returnable Containers, Solvent by Type, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents
  • {SNA} Acetone, Amber Glass Bottles, Lipid, Solvent by Type, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents, Spectrophotometric Grade,
  • {SNA} Electr

产品应用

  • 是常用有机溶剂,在显微镜分析中用作固定剂,色层分析用试剂。动物中各种成分的抽提,具有选择性地溶解某些有机物。水溶液中有丙酮存在时,可抑制溶液中物质离解, 可用于带有硫氰根的钴及铁之比色测定;显色反应检验钡、锶。显微分析用作固定剂,组织的硬化及脱水。动植物中各种成分的抽提。

相关文献及参考

  • Precursor of dimethyldioxirane, by reaction with K monopersulfate, and isolation in solution by low temperature distillation. For details, see: Chem. Ber., 124, 2377 (1991). It is an excellent reagent for rapid, stereospecific epoxidation of alkenes under mild conditions: J. Org. Chem., 50, 2847 (1985); Org. Synth. Coll., 9, 288 (1998). For improved work-up procedure allowing the possibility of more concentrated solutions or the isolation of acetone-free material, see: Tetrahedron Lett., 37, 3585 (1996). For biphasic, environmentally-friendly system (EtOAc-H2 O), see: Org. Process Res. Dev., 6, 407 (2002). Selective oxidation of phosphorus ylides occurs under mild conditions, providing a route to vicinal tricarbonyl derivatives: J. Org. Chem., 60, 8231 (1995). For conversion of ɑ-bromo-ß-dicarbonyls to vicinal tricarbonyls, see: Tetrahedron Lett., 36, 7735 (1995). For formation of singlet oxygen by deoxygenation of heteroaromatic N-oxides, e.g. 4-diethylaminopyridine N-oxide, see: J. Chem. Soc., Chem. Commun., 1831 (1995). For reviews of dioxiranes, see: Acc. Chem. Res., 22, 205 (1989); Chem. Rev., 89, 1187 (1989).
  • Merck: 14,66 Beilstein: 1,IV,3180
  • Merck: 14,66

安全信息

GHS Symbol
WGK Germany1
Hazard Codes F;Xi F,Xi
Hazard statements
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSAL3150000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P403+P235
  • P370+P378
  • P304+P340+P312
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P337+P313
Signal word Danger
UN Number UN 1090 3/PG 2
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36 Irritating to eyes 刺激眼睛
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Packing GroupII
Storage condition 避免阳光和紫外线照射,4℃下冷藏保存 密封阴凉处保存。 Store at RT.
Restrict {} {} {} {} {} {} {} 易制毒化学品 易制毒
Warnings 危险化学品

其他信息

  • Acros Organics:柠檬酸一水合物 Citricacidmonohydrate,foranalysis,99.5%(5949-29-1)
  • Alfa Aesar:柠檬酸单水合物,ACS,99.0-102.0% Citric acid monohydrate, ACS, 99.0-102.0%(5949-29-1)
  • 具特臭,具辛辣甜味,易挥发,能与水、乙醇、三氯甲烷、N、N-二甲基甲酰胺、氯仿、乙醚及大多数油类混溶。易燃。半数致死量(大鼠,经口)10.7ml/kg。有刺激性
  • MSDS 信息:Citric acid monohydrate(5949-29-1).msds
  • 用途一:主要用作食品的酸味剂,也用于制备医药清凉剂、洗涤剂用添加剂等
  • 下游产品:注射用核糖核酸 --> 2-(1-吡唑基)苯甲酸 --> 3-(1H-吡唑-3-基)苯甲酸 --> 血管紧张素II --> (3S)-3-氨基丁酸叔丁酯 --> 7-[(氨苯基乙酰基)氨基]-3-氯-8-氧代-1-氮杂二环[4.2.0]辛-2-烯-2-羧酸水合物 --> 利托那韦 --> 地诺前列酮 --> 红曲 --> 柠檬酸钙 --> 枸橼酸氯米芬 --> 柠檬酸铁
  • 蒸气压:184 mm Hg ( 20 °C)
  • Sigma Aldrich:5949-29-1(sigmaaldrich)
  • 蒸气密度:2 (vs air)
  • 外观性质:无色透明斜方形结晶或白色颗粒,无气味,味酸,在干燥空气中或加热至40-50℃成无水物,在潮湿空气中微有潮解性,75℃时变软,100℃时熔融,易溶于水,能溶于醇密度:1.54 熔点: 135-152℃闪点: 173.9℃
  • 上游原料:氢氧化钠 --> 盐酸 --> 硫酸 --> 碳酸钙
  • 敏感性:Hygroscopic
  • 海关编码:29181400
  • MOL 文件:5949-29-1.mol
  • 用途二:检定铋、亚硝酸盐、氧和水,测定铝、铜、汞、镍、氧和钍、用作多价螯合剂,除去微量金属,配制缓冲溶液,测定血钾。
  • 具特臭,具辛辣甜味,易挥发,能与水、乙醇、三氯甲烷、N、N-二甲基甲酰胺、氯仿、乙醚及大多数油类混溶。易燃。半数致死量(大鼠,经口)10.7ml/kg。有刺激性。
  • 柠檬酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10007190 柠檬酸 500g 256元 2011/08/23 10007118 柠檬酸 500g 12元 2011/08/23 1000711933 柠檬酸 25kg/袋 400元

系列性分类


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