Tetraethyltin 四乙基锡

CAS 597-64-8 MFCD00009020

化学结构图

597-64-8
SMILES: CC[Sn](CC)(CC)CC

化学属性

Mol. FormulaC8H20Sn
Mol. Weight234.97
Refractive index1.4730
Boiling Point181°
Density1.187
Melting Point-112°
Flash Point53°(128°F)
SolubilityInsoluble in water. Soluble in alcohol and ether
TSCAYes

别名和识别编码

Chemical NameTetraethyltin
CAS Number597-64-8
PubChem Substance ID11704
EC Number209-906-2
MDL NumberMFCD00009020
Synonym tetraethyl-stannan Tetraethyltin, 98%, 四乙基锡, 98%, tetraethyl stannane 四乙基锡 Tetraethyltin: (Tetraethylstannane) TIN TETRAETHYL Tetraethyl tin TETRAETHYLTIN Tetraethyltin, 98%, C 40.9%, H 8.5% Zinntetraäthyl tetraethyl-Stannane C40.9%,H8.5% tetraethylstannane Tetraethylzinn (C2H5)4Sn Tetraethyltin(IV) Tin, tetraethyl- 四乙錫 tetraethyltin Tetraethylstannane tin, tetraethyl- tetraethyl-ti tetraethyl-stannane Zinntetraethyl Stannane, tetraethyl-
Chemical Name Translation四乙基锡
Wiswesser Line Notation2-SN-2&2&2
Beilstein Registry Number3600335
InChIInChI=1S/4C2H5.Sn/c4*1-2;/h4*1H2,2H3;
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分类

  • Chemical Synthesis, Organometallic Reagents, Organotin, Organotins
  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins

相关文献及参考

  • Aldrich MSDS 1 , 1663:A / Corp MSDS 1 (2), 3263:C / FT-IR 1 (2), 1143:C / FT-IR 2 (3), 4478:C / RegBook 1 (2), 3043:G / Sax 6 , 2526 / Structure Index 1 , 481:C:7 / Vapor Phase 3 , 1681:C
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of m

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+,N
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
RTECSWH8625000
UN Number UN 3384 6.1/PG 1 UN3384
Risk Statements
  • R10 Flammable 易燃
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
  • R50/53
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S27/28
Packing GroupI
Hazard Class6.1
Storage condition Refrigerator (+4°C) + Poison room
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 39800 ug/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - muscle weakness
   Behavioral - coma
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 32(4),11,1967

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 31300 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,234,1952

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Vascular - regional or general arteriolar or venous dilation
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 10,16,1955

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 37 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - muscle weakness
   Nutritional and Gross Metabolic - weight loss or decreased weight gain

其他信息

  • 四乙基锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 212070250 四乙基锡 Tetraethyltin 97% 25 ML 3400元 2010/06/21 212070050 四乙基锡 Tetraethyltin 97% 5 ML 1079元
  • Sigma Aldrich:597-64-8(sigmaaldrich)
  • Acros Organics:四乙基锡 Tetraethyltin, 97%(597-64-8)
  • TSCA:No
  • Alfa Aesar:Tetraethyltin, 98%(597-64-8)
  • MOL 文件:597-64-8.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡
  4. Organotins - Organotin
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡
  4. Organotin Oxides

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