Bis(Tributyltin) Oxide 三丁基氧化锡
CAS 56-35-9 MFCD00009418
化学结构图
SMILES:
化学属性
| Mol. Formula | C24H54OSn2 |
|---|---|
| Mol. Weight | 596 |
| Refractive index | 1.486 |
| Boiling Point | 180 |
| Density | 1.17 |
| Flash Point | 168°(334°F) |
| TSCA | Yes |
| Melting Point | -45° |
| Vapor Pressure | <;0.01 mmHg ( 25 °C) |
| Solubility | 不溶 |
| Stability | 对空气和湿度敏感 |
| Appearance | 微黄色液体。 不溶于水，可与有机溶剂混溶。 |
别名和识别编码
| Chemical Name | Bis(Tributyltin) Oxide |
|---|---|
| Synonym | BIS(TRIBUTYLTIN) OXIDE Bis-(tributylzinn)-oxid Kyslicnik tri-n-butylcinicity {Chem { Bis(tri-n-butyltin)oxide Oxybis[tributyltin] MT 1E Bis-(tri-n-butylcin)oxid Tin, oxybis(tributyl- Bis(tributylstannyl)oxide Bis(tri-n-butylzinn)oxid Lastanox F Biomet TBTO Aceto T Bis(tributyloxide) of tin Stannicide A Oxybis(tributyltin) Bis(tributylzinn)-oxid 双(三正丁基锡)氧化物,97% ZK 21995 {uni_ha 双[三正丁基锡(IV)]氧化物 Stannane, tri-N-butyl-, oxide BTO Bis(tr Oxybis-(tributylzinn) HEXABUTYLDISTANNOXANE {uni_hamburg {SNA} Hexabutyldistanniox 1,1,1,3 双(三正丁基锡)氧化物 |
| CAS Number | 56-35-9 |
| PubChem Substance ID | 24891834 |
| EC Number | 200-268-0 |
| Beilstein Registry Number | 745057 |
| MDL Number | MFCD00009418 |
| Chemical Name Translation | 三丁基氧化锡 |
| Wiswesser Line Notation | 4-SN-4&4&O-SN-4&4&4 |
| LabNetwork Molecule ID | LN01264936 |
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分类
- {uni_hamburg} no charge; metal-organic; 1fragment
- {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotin Oxides
- {SA} 2000/60/EC, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152,
- 2000/60/EC, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152, Fungicides, Method Specific, Molluscicides, Organotins, Pesticides, Pesticides
相关文献及参考
- Reacts with alcohols to give tri-n-butylstannyl ethers which, for simple alcohols, are very susceptible to hydrolysis: Synthesis, 56 (1969); J. Organomet. Chem., 110, C57 (1976). In combination with bromine or NBS, allylic, benzylic and secondary alcohols are oxidized to carbonyl compounds, enabling the selective oxidation of secondary, in the presence of primary, alcohols: Bull. Chem. Soc. Jpn., 49, 1656 (1976); Tetrahedron Lett., 4597 (1976); J. Am. Chem. Soc., 98, 1629 (1976). Similarly, sulfides give sulfoxides with no over-oxidation to sulfones: Tetrahedron Lett., 2413 (1977).
- Short: IV/16
- Reagent for mild, selective non-hydrolytic deprotection of esters: Tetrahedron Lett., 32, 4239 (1991); J. Org. Chem., 59, 7259 (1994); Tetrahedron Lett., 36, 3311 (1995).
- Converts thioamides to nitriles, as does Di-n-butyltin oxide, L14491: J .Org. Chem., 47, 4594 (1982).
- Reacts with terminal alkynes to give alkynyl tin reagents. Where these reagents have electron-withdrawing substituents, they undergo regioselective cycloaddition with 1,3-dienes: Tetrahedron, 45, 1145 (1989):
- Shor
- Beilstein: 4,IV,4331
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H301 Toxic if swallowed 吞食有毒
- H312 Harmful in contact with skin 皮肤接触有害
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H319 Causes serious eye irritation 严重刺激眼睛
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 36500 mg/kg/2Y-C TOXIC EFFECTS : Tumorigenic - neoplastic by RTECS criteria Endocrine - tumors REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571285
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 37100 mg/kg/2Y-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Endocrine - tumors Endocrine - thyroid tumors REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 28,179,1990
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOS
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 55 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 41(5),10,1976
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 200 mg/m3 TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold Behavioral - aggression Lungs, Thorax, or Respiration - dyspnea REFERENCE : EJTXAZ European Journal of Toxicology and Environmental Hygiene. (Paris, France) V.7-9, 1974-76. For publisher information, see TOERD9. Volume(issue)/page/year: 9,339,1976
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 87 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1255,1986
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 5 mg/kg TOXIC EFFECTS : Behavioral - coma Gastrointestinal - alteration in gastric secretion Nutritional and Gross Metabolic - other changes REFERENCE : NTIS** National Technical Information Service. (Spr
TYPE OF TEST
TYPE OF TEST : DNA inhibition TEST SYSTEM : Microorganism - not otherwise specified DOSE/DURATION : 56200 ppb REFERENCE : AEMIDF Applied and Environmental Microbiology. (American Soc. for Microbiology, 1913 I St., NW, Washington, DC 20006) V.31- 1976- Volume(issue)/page/year: 45,48,1983
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Microorganism - not otherwise specified DOSE/DURATION : 56200 ppb REFERENCE : AEMIDF Applied and Environmental Microbiology. (American Soc. for Microbiology, 1913 I St., NW, Washington, DC 20006) V.31- 1976- Volume(issue)/page/year: 45,48,1983
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 100 ug/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterda
TYPE OF TEST : Micronucleus test ROUTE OF EXPOSURE : Oral TEST SYSTEM : Rodent - mouse DOSE/DURATION : 60 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 188,65,1987
TYPE OF TEST : DNA damage TEST SYSTEM : Bacteria - Bacillus subtilis DOSE/DURATION : 100 ug/disk REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 280,195
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 15 ug/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 300,5,1993
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 150 mg/kg SEX/DURATION : female 6-20 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Effects on Embryo or Fetus - fetal death REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 97,113,1989
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE : 400 mg/kg SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 50,257,1990
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE : 50 mg/kg SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetal death REFERENCE : TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 50,257,1990
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERV
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent -
其他信息
- Sigma Aldrich:56-35-9(sigmaaldrich)
- 海关编码:29310095
- 用途一:用作消毒杀菌剂、防霉剂等
- 方法一:锡和氯气反应合成四氯化锡，再与氯丁烷和金属镁反应生成三丁基氯化锡。然后用氢氧化钠处理制得氧化双三丁基锡。工业产品含量93-95%。原料消耗定额：锡800kg/t、镁500kg/t、丁醇800kg/t。
- 急性毒性:口服- 大鼠 LD50: 87 毫克/ 公斤; 口服- 小鼠 LD50: 55 毫克/ 公斤
- 三丁基氧化锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010253 三丁基氧化锡 100g 200元 2010/06/21 106510050 三丁基氧化锡 Bis(tri-n-butyltin) oxide 96%, stabilized 5 ML 316元 2010/06/21 106511000 三丁基氧化锡 Bis(tri-n-butyltin) oxide 96%, stabilized 100 ML 392元
- 灭火剂:干粉、泡沫、砂土
- Alfa Aesar:双(三正丁基锡)氧化物,97% Bis(tri-n-butyltin) oxide, 97%(56-35-9)
- Acros Organics:双(三正丁基锡)氧化物 Bis(tri-n-butyltin) oxide, stabilized, 96%(56-35-9)
- 蒸气压:<;0.01 mm Hg ( 25 °C)
- 下游产品:4-硝基苯基-D-吡喃葡糖苷 --> 2-氯-4-硝基苯-alpha-L-岩藻糖苷
- 不溶于水。
- 可燃性危险特性:受热分解排放含锡化物辛辣刺激气体
- MOL 文件:56-35-9.mol
- 用途二:用来合成有机锡高分子树脂，制取用于船舶漆的防污剂、熏蒸剂、杀菌剂、杀藻剂。
- 敏感性:Air & Moisture Sensitive
- TSCA:Yes
- 储运特性:库房通风低温干燥; 与食品原料分开储运
- 类别:农药
- 上游原料:镁 --> 1-氯丁烷 --> 三丁基氯化锡
- 职业标准:TWA 0.1 毫克 (锡)/ 立方米; STEL 0.2 毫克 (锡)/ 立方米
- 毒性分级:高毒
- 刺激数据:眼睛- 兔子 0.05 毫克/ 24小时 重度
- MSDS 信息:Hexabutyldistannoxane(56-35-9).msds
- 图谱信息:三丁基氧化锡(56-35-9)红外图谱(IR1) 三丁基氧化锡(56-35-9)核磁图( 1 HNMR) 三丁基氧化锡(56-35-9)质谱(MS)
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