N,N-Disuccinimidyl Carbonate N.N-二琥珀酰亚胺基碳酸酯

CAS 74124-79-1 MFCD00009767

化学结构图

74124-79-1
SMILES: O=C(ON1C(=O)CCC1=O)ON1C(=O)CCC1=O

化学属性

Mol. FormulaC9H8N2O7
Mol. Weight256
Melting Point190-215
Density1.422
TSCANo
Stability易吸潮

别名和识别编码

Chemical NameN,N-Disuccinimidyl Carbonate
CAS Number74124-79-1
PubChem Substance ID676246
EC Number277-730-3
Beilstein Registry Number1499137
MDL NumberMFCD00009767
Chemical Name TranslationN.N-二琥珀酰亚胺基碳酸酯
Reaxys-RN1499137
Synonym
LabNetwork Molecule IDLN00170056
InChIKeyPFYXSUNOLOJMDX-UHFFFAOYSA-N
InChIInChI=1S/C9H8N2O7/c12-5-1-2-6(13)10(5)17-9(16)18-11-7(14)3-4-8(11)15/h1-4H2
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分类

  • {SNA} Active Esters/Additives, Analytical Reagents, Analytical/Chromatography, Chemical Biology, Chemical Synthesis, Coupling, Derivatization Reagents, Derivatization Reagents HPLC, Peptide Chemistry, Peptide Coupling, Synthetic Reagents, UV-VIS
  • Active Esters/Additives, Analytical Reagents, Analytical/Chromatography, Chemical Biology, Chemical Synthesis, Coupling, Deriv
  • {SNA} Active Esters/Additives, Chemical Biology, Chemical Synthesis, Coupling, Derivatization Reagents, Derivatization Reagents HPLC,

产品应用

  • 用于N-基团保护的氨基酸和其它酸的N-琥珀酰亚胺酯制备的常用试剂;用于激活的碳酸盐,如合成尿素。

相关文献及参考

  • 1. J. Org. Chem. 71 , 9556, (2006) 摘要
  • Tetrahedron Lett. 33 , 2781, (1992)
  • J. Chem. Soc., Chem. Commun. , 1308, (1992)
  • Fieser 9 ,208 / Fieser 11 ,226
  • Aldrich MSDS 1 , 837:C / Corp MSDS 1 (1), 1478:C / FT-IR 1 (1), 796:D / FT-IR 2 (1), 1352:B / RegBook 1 (1), 931:L / Structure Index 1 , 145:C:3

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn Xn,Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+P313
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
Signal word Danger
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
Storage condition 0-10 0-10°C 易吸潮。储存温度-20°C

系列性分类


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