1,4,7,10-Tetrathiacyclododecane 1,4,7,10-四硫环十二烷

CAS 25423-56-7 MFCD00010829

化学结构图

25423-56-7
SMILES: C1CSCCSCCSCCS1

化学属性

Mol. FormulaC8H16S4
Mol. Weight240.47
Boiling Point160-162 °C/0.5 mmHg(lit.)
Melting Point226-228 °C(lit.)

别名和识别编码

Chemical Name1,4,7,10-Tetrathiacyclododecane
Synonym NSC 295589 四硫环十二烷 1,4,7,10-四硫环十二烷 NSC 295589 Tetrathia-12-crown-4 四硫环十二烷 Tetrathia-12-crown-4
MDL NumberMFCD00010829
PubChem Substance ID24856856
CAS Number25423-56-7
Chemical Name Translation1,4,7,10-四硫环十二烷
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Other Heterocyclic Building Blocks, S-Containing
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Others, S-Containing
  • Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Others, S-Containing

相关文献及参考

  • 1. C. A. Gamelas, et al., Indenyl ring slippage in crown thioether complexes [IndMo(CO)2L]+ and C-S activation of trithiacyclononane: Experimental and theoretical studies Dalton Trans. 40 , 10513-10525, (2011)
  • 2. A. Semnani, et al., Thermodynamic study of the complexation of some thiacrown ethers and iodine monobromide in carbon tetrachloride solution Heterocycl. Comm. 14 , 307-318, (2008)
  • 3. M. F. Davis, et al., Tungsten(VI) and molybdenum(VI) complexes with soft thioether ligand coordination - synthesis, spectroscopic and structural studies Eur. J. Inorg. Chem. 13 , 1903-1910, (2007)
  • 4. C. D. Beard, et al., Studies on chromium(III) and vanadium(III) complexes with crown ether and crown thioether coordination - synthesis, properties and structural systematics Eur. J. Inorg. Chem. 21 , 4399-4406, (2006)
  • 5. N. Shan, et al., Ruthenium (II) thiacrown complexes as hydrogen-transfer reduction catalysts Inorg. Chim. Acta 359 , 759-765, (2006)
  • Corp MSDS 1 (2), 3312:B / FT-IR 2 (1), 438:A / FT-NMR 1 (1), 437:A / RegBook 1 (1), 289:J

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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