Mercury(II) cyanide 氰化汞(II)

CAS 592-04-1 MFCD00011037

化学结构图

592-04-1
SMILES: N#C[Hg]C#N

化学属性

Mol. FormulaC2HgN2
Mol. Weight252.63
Density3.996 g/mL at 25 °C(lit.)
Solubility易溶于水、氨水、甲醇、乙醇,不溶于苯。

别名和识别编码

Chemical NameMercury(II) cyanide, 99%
Synonym {uni_hamburg} Mercury dicyanide 氰化高汞 MERCURY(+2)CYANIDE CIANURINA dicyanomercury cyanuredemercure Cyanure de mercure MERCURICCYANIDE,REAGENT Mercury (II) cyanide Mercuric cyanide (Hg(CN)2) Dicyanomercury(II) Mercury(II)cyanide,99% hydrocyanic acid; mercury(II) salt 氰化汞 Mercury (II) cyanide, 99.7% Quecksilber(II)-cyanid Quecksilber-II-cyanid Mercury(II)cyanide Mercury cyanide (Hg(CN)2) Mercury cyanide Mercury(II)dicyanide mercurydicyanide MERCURY(II) CYANIDE 氰化汞(II) Quecksilbercyanid MERCURY CYANIDE Mercuric cyanide Mercury(II) cyanide Cianurina cyanuredemercure(french) mercurycyanide(hg(cn)2) Mercury cyanide (Hg(CN)2) Mercuric cyanide (Hg(CN)2) MERCURY(II) CYANIDE 99% MERCURIC CYANIDE Dicyanomercury Quecksilber(II)cyanid
EC Number209-741-6
Beilstein Registry Number4652800
MDL NumberMFCD00011037
PubChem Substance ID11591
CAS Number592-04-1
Chemical Name Translation氰化汞(II)
Merck Number13,5903
Wiswesser Line NotationHG CN2
LabNetwork Molecule IDLN00196059
InChIInChI=1S/2CN.Hg/c2*1-2;
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Materials Science, Mercury Salts, Metal and Ceramic Science, Salts

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupt

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H300+H310+H330
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
RTECSOW1515000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S29 Do not empty into drains 不要排入下水道;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
Hazard Codes T+,N
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R50/53
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
Packing GroupII
Hazard Class6.1(a)
Storage condition Poison room
UN Number UN 1636 6.1/PG 2
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 27 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - hypermotility, diarrhea
   Gastrointestinal - nausea or vomiting
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   CTOXAO Clinical Toxicology.  (New York, NY)  V.1-18, 1968-81.  For publisher
   information, see JTCTDW.  Volume(issue)/page/year: 11,301,1977

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 41,21,1931

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 71400 ug/kg
TOXIC EFFECTS :
   Cardiac - pulse rate increase, without fall in BP
   Vascular - BP lowering not characterized in autonomic section
   Kidney, Ureter, Bladder - urine volume decreased
REFERENCE :
   ICMED9 Intensive Care Medicine.  (Springer-Verlag New York, Inc., Service
   Center, 44 Hartz Way, Secaucus, NJ 07094)  V.3-    1977-
   Volume(issue)/page/year: 21,1051,1995

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 26 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(i

其他信息

  • Sigma Aldrich:592-04-1(sigmaaldrich)
  • 爆炸物危险特性:摩擦, 受热, 冲击灵敏爆炸
  • 类别:农药
  • 毒性分级:剧毒
  • MSDS 信息:氰化汞(592-04-1).msds
  • F:8
  • 外观性质:无色或白色结晶粉末,见光颜色变暗。
  • 下游产品:更昔洛韦
  • 急性毒性:口服- 大鼠 LD50: 26 毫克/ 公斤; 口服- 小鼠 LD50: 33 毫克/ 公斤
  • MOL 文件:592-04-1.mol
  • 储运特性:库房通风低温干燥; 与碱、酸类、食品添加剂分开存放
  • Acros Organics:氰化汞 Mercury(II)cyanide,99%(592-04-1)
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 9.3g/20℃
  • 灭火剂:二氧化碳, 干粉, 泡沫
  • 职业标准:TLA-TWA 0.1 毫克 (汞)/ 立方米; STEL 0.15 毫克 (汞)/ 立方米
  • 可燃性危险特性:不可燃物质; 遇水、酸放出有毒易燃氰化氢气体; 受热产生有毒氰化物和汞蒸气

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