Vanadium(III) Oxide 氧化钒(III)

CAS 1314-34-7 MFCD00011455

化学结构图

1314-34-7
SMILES: O=[V]O[V]=O

化学属性

Mol. FormulaV2O3
Mol. Weight149.88
Density4.87 g/mL at 25 °C(lit.)
Melting Point1970 °C (lit.)
SolubilityInsoluble in water
TSCAYes

别名和识别编码

Chemical NameVanadium(III) Oxide
MDL NumberMFCD00011455
PubChem Substance ID24870091
CAS Number1314-34-7
EC Number215-230-9
Synonym {uni_hamburg} Vanadium oxide (V2O3) vanadiumoxide(v2o3) V2-O3 Vanadic oxide 五氧化二钒 vanadicoxide Divanadiumtrioxid VANADIUM (V) PENTOXIDE VANADIUM TRIOXIDE Vanadium oxide VANADIUM(V) OXIDE Vanadiumtrioxid 三氧化钒 Vanadium trioxide, V2O3 VANADIUM(+5)OXIDE VANADIUM OXIDE 氧化钒(III), 99.7% (METALS BASIS) c.i. 77938 VANADIUM (III) OXIDE 五氧化二釩 三氧化二钒(III) Vanadium(III)-oxid Divanadium pentaoxide 氧化钒(III) VANADIUM(+3)OXIDE 钒酸酐 VANADIC ACID Vanadium(III) oxide VANADIC ANHYDRIDE Vanadium trioxide {Che
Merck Number14,9923
Chemical Name Translation氧化钒(III)
Wiswesser Line NotationVA2 O3
LabNetwork Molecule IDLN00193567
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分类

  • {SNA} 12 Principles Aligned Products, Alternative Energy, Anode Materials, Catalysis and Inorganic Chemistry, Chemical Synthesis, Electrode Materials, Greener Alternative Products, Material Sciences
  • {SNA} Alternative Energy, Anode Materials, Catalysis and Inorganic Chemistry, Chemical Synthesis, Electrode

相关文献及参考

  • Short: III/13a
  • Short: III/20b
  • Short: III/23b

安全信息

WGK Germany3
Precautionary statements
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
RTECSYW3050000
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H310 Fatal in contact with skin 皮肤接触致命
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xn
GHS Symbol
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Danger Warning
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
UN Number UN 2862 6.1/PG 3 UN3285
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20 Harmful by inhalation 吸入有害
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R36 Irritating to eyes 刺激眼睛
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
Packing GroupII
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 566 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Liver - other changes
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534591

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534591

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intratracheal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AEC-TR-6710

TYPE OF TEST            : LD50 - Lethal dose, 50 percent ki

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 1470 ug/L
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 50,327,1990

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 18 mg/L
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 50,327,1990

其他信息

  • 毒性分级:剧毒
  • Alfa Aesar:氧化钒(III),99.7%(metalsbasis) Vanadium(III) oxide, 99.7% (metals basis)(1314-34-7)
  • Sigma Aldrich:1314-34-7(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与酸类, 食品分开储运
  • MOL 文件:1314-34-7.mol
  • 灭火剂:水, 砂土
  • MSDS 信息:三氧化二钒(1314-34-7).msds
  • 三氧化二钒(III)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 43377 氧化钒(III), 99.7% (metals basis) Vanadium(III) oxide, 99.7% (metals basis) 100g 2716元 2010/05/25 12301 氧化钒(III), 95% Vanadium(III) oxide, 95% 5kg 6944元 2010/05/25 12301 氧化钒(III), 95% Vanadium(III) oxide, 95% 250g 566元
  • 可燃性危险特性:在空气中可自燃; 火场产生含钒化合物烟雾
  • 图谱信息:三氧化二钒(III)(1314-34-7)红外图谱(IR1)
  • 急性毒性:口服-小鼠 LD50: 23 毫克/公斤
  • 职业标准:TWA 0.5 毫克 (五氧化二钒)/立方米
  • 外观性质:灰黑色结晶或粉末。
  • 类别:有毒物品

系列性分类


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