Tetraphenylphosphonium Chloride 四苯基氯化膦

CAS 2001-45-8 MFCD00011916

化学结构图

2001-45-8
SMILES: [Cl-].c1ccc([P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC24H20ClP
Mol. Weight374.84
Melting Point272-274°C
TSCANo
Appearance 白色至类白色晶体, 熔点275-280℃

别名和识别编码

Chemical NameTetraphenylphosphonium Chloride
MDL NumberMFCD00011916
CAS Number2001-45-8
PubChem Substance ID164911
Beilstein Registry Number3922393
EC Number217-890-3
Synonym Tetraphenylphosphonium chloride {LY} Tetraphenylphosphonium chloride {} {LY} Tetraphenylphosphonium chloride {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation四苯基氯化膦
Reaxys-RN3922393
InChIKeyWAGFXJQAIZNSEQ-UHFFFAOYSA-M
LabNetwork Molecule IDLN00202511
InChIInChI=1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
Canonical SMILESC1([P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)=CC=CC=C1.[Cl-]
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分类

  • {SNA} Chemical Synthesis, Phase Transfer Catalysts, Phosphonium Salts, Synthetic Reagents

相关文献及参考

  • High-temperature phase-transfer catalyst (see Appendix 2). In combination with Bis(acetonitrile)­dichloropalladium(II)­, 10002, provides an effective catalyst for the Heck reaction of normally unreactive aryl halides, e.g. chlorobenzene with styrene to give stilbene. The reaction is performed at 140-150o in DMF or NMP in the presence of sodium acetate. The reaction may be further improved by the addition of 10-12 mol% N,N-Dimethyl­glycine, A19670: Angew. Chem. Int. Ed., 37, 481 (1998).
  • Reagent for Bi and Co.

安全信息

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany3
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xi

其他信息

  • Sigma Aldrich:2001-45-8(sigmaaldrich)
  • 海关编码:29310095
  • MSDS 信息:Tetraphenylphosphonium chloride(2001-45-8).msds
  • TCI Shanghai:四苯基氯盐 Tetraphenylphosphonium Chloride,>;98.0%(LC)(T)(2001-45-8)
  • F:3-10
  • 用途一:医药中间体。
  • 四苯基氯化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1375 四苯基氯化 Tetraphenylphosphonium Chloride 5G 500元 2014/06/02 T1375 四苯基氯化 Tetraphenylphosphonium Chloride 25G 1490元 2010/06/21 204030100 四苯基氯化 Tetraphenylphosphonium chloride 98% 10 GR 930元
  • MOL 文件:2001-45-8.mol
  • Alfa Aesar:四苯基氯化膦,98% Tetraphenylphosphonium chloride, 98%(2001-45-8)
  • 图谱信息:四苯基氯化(2001-45-8)红外图谱(IR1) 四苯基氯化(2001-45-8)核磁图( 1 HNMR) 四苯基氯化(2001-45-8)红外图谱(IR2) 四苯基氯化(2001-45-8)质谱(MS) 四苯基氯化(2001-45-8)核磁图( 13 CNMR)
  • Acros Organics:四苯基氯化磷 Tetraphenylphosphonium chloride, 99%(2001-45-8)
  • 敏感性:Hygroscopic

系列性分类


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