CAS 593-56-6 MFCD00012951-O-Methylhydroxylamine hydrochloride, 99%, for synthesis 甲氧基胺盐酸盐 -LabNovo

O-Methylhydroxylamine hydrochloride, 99%, for synthesis 甲氧基胺盐酸盐

CAS 593-56-6 MFCD00012951

化学结构图

SMILES: CON.Cl

化学属性

Mol. Formula	CH6ClNO
Mol. Weight	83.52
Refractive index	n20/D 1.4021
Density	1.1 g/mL at 25 °C
Melting Point	151-154°C
TSCA	Yes
Solubility	可溶
Stability	易吸潮
Boiling Point	105-110 °C at 760 mmHg

别名和识别编码

Chemical Name	O-Methylhydroxylamine hydrochloride, 99%, for synthesis
CAS Number	593-56-6
Alfabeta Name	METHYLHYDROXYLAMINEHYDROCHLORIDE O-
MDL Number	MFCD00012951
Synonym	Methoxyamine (hydrochloride) {LY} Methoxyamine (hydrochloride) {} {LY} Methoxyamine (hydrochloride) {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methoxyamine (hydrochloride) {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	521874
Beilstein Registry Number	3589723
EC Number	209-798-7
Reaxys-RN	3589723
Merck Number	5989
Chemical Name Translation	甲氧基胺盐酸盐
Wiswesser Line Notation	ZO1 &GH
LabNetwork Molecule ID	LN00008853
InChI	InChI=1S/CH5NO.ClH/c1-3-2;/h2H2,1H3;1H
Canonical SMILES	NOC.[H]Cl

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产品应用

是1,4-二烯-3-酮系统中保护酮基基团的试剂；用于依靠GLC2检测类固醇酮基基团的衍生试剂；靠GC3快速检测糖蛋白中的中性糖和氨基糖；用于酮的异构选择性还原反应。

安全信息

Warnings HYGROSCOPIC, CORROSIVE

GHS Symbol

WGK Germany3

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H302 Harmful if swallowed 吞食有害
H302+H312
H312 Harmful in contact with skin 皮肤接触有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H318 Causes serious eye damage 严重伤害眼睛
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 8 C,N C,Xi,N

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P312
P301+P330+P331
P302+P352
P303+P361+P353
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P333+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R34 Causes burns 会导致灼伤

RTECSNC3980000

UN Number 3261

Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Hygroscopic Store at room temperature {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {L

Packing GroupII

Hazard Class8

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 900 mmol/L
REFERENCE :
   DKBSAS Doklady Biological Sciences (English Translation).  Translation of
   DANKAS: Biological Section. (Plenum Pub. Corp., 233 Spring St., New York, NY
   10013)  V.112-    1957-  Volume(issue)/page/year: 257,154,1981

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Cells - not otherwise specified
DOSE/DURATION           : 2 gm/L
REFERENCE :
   SOGEBZ Soviet Genetics.  English translation of GNKAA5.  (Plenum Pub. Corp.,
   233 Spring St., New York, NY 10013)  V.2-    1966- Volume(issue)/page/year:
   11,480,1975

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Parenteral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 10 mmol/L
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   2,331,1970

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 1 mol/L
REFERENCE :
   BBACAQ Biochimica et Biophysica Acta.  (Elsevier Science Pub. B.V., POB 211,
   1000 AE Amsterdam, Netherlands)  V.1-    1947- Volume(issue)/page/year:
   39

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURA

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Cells - not otherwise specified
DOSE/DURATION           : 2 gm/L
REFERENCE :
   SOGEBZ Soviet Genetics.  English translation of GNKAA5.  (Plenum Pub. Corp.,
   233 Spring St., New York, NY 10013)  V.2-    1966- Volume(issue)

其他信息

MSDS 信息:Methoxyammonium chloride(593-56-6).msds
图谱信息:甲氧基胺盐酸盐(593-56-6)质谱(MS) 甲氧基胺盐酸盐(593-56-6)红外图谱(IR2) 甲氧基胺盐酸盐(593-56-6)核磁图( 13 CNMR) 甲氧基胺盐酸盐(593-56-6)核磁图( 1 HNMR) 甲氧基胺盐酸盐(593-56-6)Raman光谱甲氧基胺盐酸盐(593-56-6)红外图谱(IR1)
用途一:用作甲氧胺基化试剂，也用于生产药物头孢呋新侧链和其它新药
甲氧基胺盐酸盐价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 M0886 O-甲氧胺盐酸盐(约40%的水溶液,约5.4mol/L) O-Methylhydroxylamine Hydrochloride (ca. 40% in Water, ca. 5.4mol/L) 25ML 398元 2014/06/02 M0886 O-甲氧胺盐酸盐(约40%的水溶液,约5.4mol/L) O-Methylhydroxylamine Hydrochloride (ca. 40% in Water, ca. 5.4mol/L) 500ML 3310元 2014/06/02 M0343 O-甲基羟胺盐酸盐 O-Methylhydroxylamine Hydrochloride 25G 457元
检测方法:T,NMR,HPLC(Differential)
下游产品:3-氨基-4-硝基吡啶
MOL 文件:593-56-6.mol
Alfa Aesar:甲氧胺盐酸盐,98+% Methoxylamine hydrochloride, 98+%(593-56-6)
F:3-10
敏感性:Hygroscopic
Sigma Aldrich:593-56-6(sigmaaldrich)
甲氧胺盐酸盐:甲氧胺盐酸盐又称为O-甲基羟胺盐酸盐;甲氧基胺;甲氧胺盐酸盐 (OMHA)，是一种重要医药、农药中间体，主要用途如下： 1，用于彩色照相和影片的洗印。 2，有机合成工业作还原剂制备肟类。 3，医药领域：合成第二代头孢类抗生素头孢呋辛（酯）、新诺明、炔诺明和羟基脲。 4，农药领域：合成新型高效低毒杀菌剂苯氧菌胺。国内多采用亚硝酸钠法生产。甲氧胺盐酸盐的同类化合物乙氧胺盐酸盐主要用于生产苯草酮、烯草酮、稀禾定等除草剂。
溶于水和醇。
Acros Organics:甲氧胺盐酸盐 Methoxylamine hydrochloride, 98+%(593-56-6)
用途二:是1,4-二烯-3-酮系统中保护酮基基团的试剂；用于依靠GLC2检测类固醇酮基基团的衍生试剂；靠GC3快速检测糖蛋白中的中性糖和氨基糖；用于酮的异构选择性还原反应。
TCI Shanghai:甲氧基胺盐酸盐 O-Methylhydroxylamine Hydrochloride,>;97.0%(T)(N)(593-56-6)
Hazard Note:Corrosive/Hygroscopic

O-Methylhydroxylamine hydrochloride, 99%, for synthesis 甲氧基胺盐酸盐

CAS 593-56-6 MFCD00012951

化学结构图

化学属性

别名和识别编码

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产品应用

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化学结构图

化学属性

别名和识别编码

分类

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相关文献及参考

安全信息

其他信息

系列性分类

相关产品推荐

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