Aluminum Sulfide 硫化铝

CAS 1302-81-4 MFCD00014162

化学结构图

1302-81-4
SMILES: S=[AlH3]S[AlH3]=S

化学属性

Mol. FormulaAl2S3
Mol. Weight150.16
Density2.02 g/mL at 25 °C(lit.)
Melting Point1100 °C
TSCAYes
Appearance granular
Boiling Point

别名和识别编码

Chemical NameAluminum Sulfide
Synonym Aluminumsulfide {LY} Aluminumsulfide {} {LY} Aluminumsulfide {} {} {LY} Aluminumsulfide {} {} {} {LY} Aluminumsulfide {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminumsulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00014162
CAS Number1302-81-4
PubChem Substance ID159369
EC Number215-109-0
Merck Number14,367
Chemical Name Translation硫化铝
Canonical SMILESS=[Al][Al]=S=S
Beilstein Registry Number
InChIInChI=1S/2Al.3S/q2*+3;3*-2
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分类

  • {uni_hamburg}
  • {SNA} Chalcogenides, Materials Science, Metal and Ceramic Science
  • {SNA} Chalcogenides, Metal and Ceramic Science, 材料科学

相关文献及参考

  • Short: III/12b
  • Short: III/14b1
  • Short: III/6
  • Short: IV/19A1

安全信息

WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S8 Keep container dry 保持容器干燥；
Packing GroupIII
UN Number UN3134
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R31 Contact with acids liberates toxic gas 与酸接触释放出有毒气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
Hazard Codes Xi
Precautionary statements
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P335+P334
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P337+P317
  • P362+P364
  • P370+P378
  • P402+P404
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
GHS Symbol
Hazard Class4.3
RTECS

其他信息

  • Sigma Aldrich:1302-81-4(sigmaaldrich)
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:硫化铝,99+%,(metalsbasis) Aluminum sulfide, 99+%, (metals basis)(1302-81-4)
  • MOL 文件:1302-81-4.mol
  • 外观性质:纯品为白色针状晶体，通常见到的不纯物为黄灰色致密的物质。硫化铝在热水中完全水解生成氢氧化铝沉淀和硫化氢。在潮湿空气中也能水解，因而有硫化氢气味。密度：2.02熔点：1100℃

系列性分类

  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Chalcogenides - Metal and Ceramic Science