Tetramethylgermanium 四甲基锗

CAS 865-52-1 MFCD00014843

化学结构图

865-52-1
SMILES: C[Ge](C)(C)C

化学属性

Refractive index1.3870 to 1.3900
TSCANo
Vapor Pressure6.74 psi ( 20 °C)
Mol. FormulaC4H12Ge
Mol. Weight133
Density0.978
Flash Point-35°F
Appearance colorless liq.
Boiling Point43.4°C
Melting Point-88°C

别名和识别编码

Chemical NameTetramethylgermanium
Synonym 四甲基锗 (CH3)4Ge GERMANIUM TETRAMETHYL TETRAMETHYLGERMANIUM tetramethylgermane Tetramethylgermanium,98% TL 81 TETRAMETHYLGERMANE tetramethyl-germane tetramethyl germanium germane, tetramethyl- TETRAMETHYLGERMANIUM SOLUTION, ~2.9 M IN THF Tetramethylgermanium tetramethylgermanium Tetramethylgermane,99% Tetramethylgermanium solution tl81 tetramethyl-germaniu Tetralmethylgermanium
PubChem Substance ID70079
EC Number212-745-0
Reaxys-RN3660066
Chemical Name Translation四甲基锗
InChIKeyZRLCXMPFXYVHGS-UHFFFAOYSA-N
Beilstein Registry Number3660066
LabNetwork Molecule IDLN01247179
InChIInChI=1S/C4H12Ge/c1-5(2,3)4/h1-4H3
MDL NumberMFCD00014843
CAS Number865-52-1
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} CVD and ALD Precursors by Metal, Chemical Synthesis, Germanium, Materials Science, Micro/NanoElectronics, Organogermanium, Organometallic Reagents, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal, Chemical Synthesis, Germanium, Micro/NanoElectronics, Organogermanium, Organometallic Reagents, Vapor Deposition Precursors, 材料科学

相关文献及参考

  • Short: II/25C Title: Structure Data Of Free Polyatomic Molecules: Molecules containing Three or Four Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25C Year: 2001 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-66774-1 ISBN: 978-3-540-66774-2 Internet Resource: DOI:10.1007/b71431 RefComment: VIII, 481 pages. Hardcover Abstract: This volume contains data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc.) of free polyatomic molecules including free radicals and molecular ions. This survey on structure data is made of four subvolume, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this third subvolume, the structure of molecules containing three for four carbon atoms are listed.
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling consta

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,Xn
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSLY5345000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P337+P313
  • P337+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger {} {} {} {} {} {} {} {} {TCI}
UN Number UN 1993 3/PG 2 UN1993 1993
Storage condition 0-10 Flammables area 0-10°C
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36 Irritating to eyes 刺激眼睛
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Packing GroupII
Hazard Class3 
TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >2500 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,Mar,1942

其他信息

  • 图谱信息:四甲基锗(865-52-1)质谱(MS) 四甲基锗(865-52-1)核磁图( 13 CNMR) 四甲基锗(865-52-1)核磁图( 1 HNMR) 四甲基锗(865-52-1)红外图谱(IR1)
  • TCI Shanghai:四甲基锗 Tetramethylgermane,>;98.0%(GC)(865-52-1)
  • MOL 文件:865-52-1.mol
  • Alfa Aesar:四甲基锗,98% Tetramethylgermanium, 98%(865-52-1)
  • 蒸气压:6.74 psi ( 20 °C)
  • TSCA:No
  • Sigma Aldrich:865-52-1(sigmaaldrich)
  • 四甲基锗价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1158 四甲基锗 Tetramethylgermane 5G 1090元 2014/06/02 T1158 四甲基锗 Tetramethylgermane 1G 365元 2010/05/25 A16931 四甲基锗, 98% Tetramethylgermanium, 98% 5g 1155元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organogermanium 有机锗
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Germanium - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. CVD & ALD Precursors
  2. Germanium
  1. Metal Alkyls
  2. Germanium

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