Tetrakis(Dimethylamino)Titanium TDMAT 四(二甲胺基)钛

CAS 3275-24-9 MFCD00014861

化学结构图

3275-24-9
SMILES: CN(C)[Ti](N(C)C)(N(C)C)N(C)C

化学属性

TSCAYes
Melting Point<4°C
Mol. FormulaTi[N(CH3)2]4
Appearance yellow to orange liq.
Mol. Weight224
Stabilitymoisture sensitive
Density0.96
Flash Point-22°F
Boiling Point50°C/0.5 mm
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameTetrakis(Dimethylamino)Titanium
Synonym Tetrakis(dimethylamino)titanium, 96% , C 44.5%, H 10.8%, Ti 26.99-29.23% TETRAKIS(DIMETHYLAMINO)TITANIUM TETRAKIS(DIMETHYLAMINO)TITANIUM, 99.999% Titantetrakis(dimethylammonium) Titanium, tetrakis(dimethylamino)- 二甲基氨基钛(IV) {uni_hambur Tetrakis(dimethylamino)titanium, 99.99% n-methyl-methanamintitanium(4+)salt Tetrakis(dimethylamino)titanium,99%TDMAT Titanium tetrakis(dimethylamide); Tetrakis(dimethylamino)titanium TDMAT 四(二甲基氨基)钛(IV) TETRAKIS(DIMETHYLAMIDO)TITANIUM(IV), FOR titanium dimethylamide Tetrakis(dimethylamino)titanium(IV) {JN TITANIUM(IV) DIMETHYLAMIDE 四次二甲基銨基鈦 tetrakis(dimethylamino)titanium 四(二甲基氨基)钛(IV) Titanium(IV) dimethylamide, 99.95%
PubChem Substance ID123185
EC Number221-904-3
Reaxys-RN3618377
Beilstein Registry Number4(4)128
Chemical Name Translation四(二甲胺基)钛
InChIKeyMNWRORMXBIWXCI-UHFFFAOYSA-N
LabNetwork Molecule IDLN01253381
CAS Number3275-24-9
MDL NumberMFCD00014861
InChIInChI=1S/4C2H6N.Ti/c4*1-3-2;/h4*1-2H3;/q4*-1;+4
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分类

  • {SNA} CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Titanium, Vapor Deposition Precursors
  • {SA} 22: Titanium, CVD and ALD Precursors Packaged for Deposition Systems, CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Titanium, Vapor Deposition Precursors
  • {SNA} CVD and ALD Precursors by Metal,

相关文献及参考

  • 1. J. Appl. Phys. 102 , 083521/1, (2007)
  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,C,Xi F,C
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P335+P334
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number UN3129 3398 3399
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R14 Reacts violently with water 遇水会猛烈反应
  • R11 Highly flammable 非常易燃
Storage condition Moisture Sensitive Flammables area
Packing GroupII
Hazard Class4.3/3
Restrict 危险品

其他信息

  • Alfa Aesar:四(二甲氨基)钛,99.9%(metalsbasis) Tetrakis(dimethylamino)titanium, 99.9% (metals basis)(3275-24-9)
  • Acros Organics:四(二甲氨基)钛 Tetrakis(dimethylamino)titanium, 99.99%(3275-24-9)
  • 四(二甲氨基)钛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2230 四(二甲氨基)钛(IV) Tetrakis(dimethylamino)titanium(IV) 5G 909元 2014/06/02 T2230 四(二甲氨基)钛(IV) Tetrakis(dimethylamino)titanium(IV) 1G 335元 2010/06/21 353560050 四(二甲氨基)钛 Tetrakis(dimethylamino)titanium 99.99% 5 GR 1042元
  • Sigma Aldrich:3275-24-9(sigmaaldrich)
  • 敏感性:Moisture Sensitive
  • MOL 文件:3275-24-9.mol
  • 四(二甲氨基)钛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 T2230 四(二甲氨基)钛(IV) Tetrakis(dimethylamino)titanium(IV) 5G 916元 2011/04/16 T2230 四(二甲氨基)钛(IV) Tetrakis(dimethylamino)titanium(IV) 1G 349元 2010/06/21 353560050 四(二甲氨基)钛 Tetrakis(dimethylamino)titanium 99.99% 5 GR 1042元
  • TCI Shanghai:四(二甲氨基)钛(IV) Tetrakis(dimethylamino)titanium(IV),>;97.0%(T)(3275-24-9)
  • TSCA:Yes

系列性分类

  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors Packaged for Deposition Systems - Vapor Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors
  2. Titanium
  1. Metal Alkylamides
  2. Titanium

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