4-Hydroxy-3,5-DIIodobenzonitrile 4-羟基-3,5-二碘苯腈

CAS 1689-83-4 MFCD00016422

化学结构图

1689-83-4
SMILES: N#Cc1cc(I)c(O)c(I)c1

化学属性

Mol. FormulaC7H3I2NO
Mol. Weight370.91
Melting Point200 °C
TSCANo
Solubility不溶
Boiling Point282.6±40.0 °C at 760 mmHg

别名和识别编码

Chemical Name4-Hydroxy-3,5-DIIodobenzonitrile
CAS Number1689-83-4
Synonym 4-Hydroxy-3,5-diiodobenzonitrile {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzonitrile {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydroxy-3,5-diiodobenzon
MDL NumberMFCD00016422
PubChem Substance ID15530
Beilstein Registry Number2364041
EC Number216-881-1
Alfabeta NameHYDROXYDIIODOBENZONITRILE 435---,
Chemical Name Translation4-羟基-3,5-二碘苯腈
Wiswesser Line NotationQR BI FI DCN
InChIInChI=1S/C7H3I2NO/c8-5-1-4(3-10)2-6(9)7(5)11/h1-2,11H
Canonical SMILESN#CC1=CC(I)=C(C(I)=C1)O
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分类

  • {SNA} 2005/70/EU, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152, H-M, I, Method and Regulation Specific, Nitriles, Pesticides, Bactericides, Fungicides and Disinfectants, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 农残和代谢标准品, 按照字母排序, 灭草剂
  • {SNA} 2005/70/EU, Additional Standards, Analytical Standards, European Community: ISO, DIN and DL 152, Food and Cosmetic Component Standards, H-M,
  • {SNA} 2005/70/EU,

产品应用

  • 3,5-Diiodo-4-hydroxybenzonitrile is used in the preparation of herbicides Bromoxynil and Ioxynil.

相关文献及参考

  • Andreasen, C., et al.: Weed Res., 46, 503 (2006),
  • Mithila, J., et al.: Weed Sci., 56, 12 (2008),
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSDI4025000
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310+P330
  • P304+P340+P312
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P301+P310
  • P305+P351+P338
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Hazard statements
  • H331 Toxic if inhaled 吸入中毒
  • H301 Toxic if swallowed 吞食有毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H301+H331
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
Hazard Codes T,N T;N N-T,N,T
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S63
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
UN Number 2811 3276 UN3439
Risk Statements
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R48/22
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36 Irritating to eyes 刺激眼睛
  • R50/53
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from l
Packing GroupIII
Warnings IRRITANT
Hazard Class6.1 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6552 mg/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0571274

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 230 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer
   Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R.,
   Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971  Volume(issue)/page/year:
   -,93,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer
   Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R.,
   Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971  Volume(issue)/page/year:
   -,93,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02818

TYPE OF TEST            : LD50 - Let

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)

其他信息

  • MSDS 信息:碘苯腈(1689-83-4).msds
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 急性毒性:口服- 大鼠 LD50: 110 毫克/ 公斤; 口服- 小鼠 LD50: 230 毫克/ 公斤
  • MOL 文件:1689-83-4.mol
  • 毒性分级:高毒
  • Alfa Aesar:3,5-二碘-4-羟基苯甲腈,97% 3,5-Diiodo-4-hydroxybenzonitrile, 97%(1689-83-4)
  • 可燃性危险特性:燃烧产生有毒氮氧化物和碘化物气体
  • Sigma Aldrich:1689-83-4(sigmaaldrich)
  • 类别:农药
  • 灭火剂:干粉、泡沫、砂土
  • 用途一:该药能被叶片吸收，抑制光合作用、呼吸作用和蛋白质合成。可防除繁缕、婆婆纳、田旋花田芥等阔叶杂草。
  • Acros Organics:3,5-碘-4-羟基苯丙腈/碘苯腈 3,5-Diiodo-4-hydroxybenzonitrile, 98%(1689-83-4)
  • 外观性质:无色固体。
  • 碘苯腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 259180050 碘苯腈 3,5-Diiodo-4-hydroxybenzonitrile 98% 5 GR 1326元 2010/05/25 A13929 3,5-二碘-4-羟基苯甲腈, 97% 3,5-Diiodo-4-hydroxybenzonitrile, 97% 5g 776元 2010/05/25 A13929 3,5-二碘-4-羟基苯甲腈, 97% 3,5-Diiodo-4-hydroxybenzonitrile, 97% 25g 2604元
  • 敏感性:Light Sensitive

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. H-M - Alpha sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. European Community: ISO, DIN and DL 152 - Method Specific
  5. 2005/70/EU - European Community: ISO, DIN and DL 152