(Chloromethyl)Methyldiethoxysilane (氯甲基)甲基二乙氧基硅烷

CAS 2212-10-4 MFCD00018878

化学结构图

2212-10-4
SMILES: CCO[Si](C)(CCl)OCC

化学属性

Mol. FormulaC6H15ClO2Si
Mol. Weight182.72
Density1.000
Flash Point38°C
Melting Point<0°C
Boiling Point161
Refractive index1.4130 to 1.4170

别名和识别编码

Chemical Name(Chloromethyl)Methyldiethoxysilane
Synonym (Chloromethyl)diethoxy(methyl)silane {LY} (Chloromethyl)diethoxy(methyl)silane {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)diethoxy(methyl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00018878
CAS Number2212-10-4
PubChem Substance ID16650
EC Number218-657-9
Chemical Name Translation(氯甲基)甲基二乙氧基硅烷
Wiswesser Line NotationG1-SI-1&O2&O2
Beilstein Registry Number1739015
InChIKeyXGLLBUISUZEUMW-UHFFFAOYSA-N
Reaxys-RN1739015
LabNetwork Molecule IDLN01364056
InChIInChI=1S/C6H15ClO2Si/c1-4-8-10(3,6-7)9-5-2/h4-6H2,1-3H3
Canonical SMILESC[Si](OCC)(CCl)OCC
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分类

  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Siloxanes
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVV2180000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Hazard Codes 3
Risk Statements
  • R10 Flammable 易燃
  • R22 Harmful if swallowed 吞咽有害
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
UN Number 1993 
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2270 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1226,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1226,1986

Packing GroupIII
Hazard Class3
Storage condition

其他信息

  • 急性毒性:口服-大鼠 LD50: 1300 毫克/ 公斤; 吸入-大鼠 LCL0: 2270 ppm/4小时
  • 可燃性危险特性:可燃;火场释放有毒氯化物和氧化硅烟雾
  • 储运特性:库房低温, 通风, 干燥
  • 毒性分级:中毒
  • MOL 文件:2212-10-4.mol
  • 类别:有毒物质
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • Sigma Aldrich:2212-10-4(sigmaaldrich)
  • 刺激数据:皮肤- 兔 20 毫克/24小时 中度; 眼睛- 兔 100 毫克/24小时 中度
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Siloxanes - Organosilicon

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