3,3-Bis(Chloromethyl)Oxetane 3,3-二(氯甲基)氧杂环丁烷

CAS 78-71-7 MFCD00027377

化学结构图

78-71-7
SMILES: ClCC1(CCl)COC1

化学属性

Mol. FormulaC5H8Cl2O
Mol. Weight155.02
Density1.29 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.486(lit.)
Boiling Point198 °C at 760 mmHg
Flash Point114°C
Melting Point18.7 °C

别名和识别编码

Chemical Name3,3-Bis(Chloromethyl)Oxetane
CAS Number78-71-7
Alfabeta NameBISCHLOROMETHYLOXETANE 33()-,
MDL NumberMFCD00027377
Synonym 3,3-Bis(chloromethyl)oxetane {LY} 3,3-Bis(chloromethyl)oxetane {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3,3-Bis(chloromethyl)oxetane {} {} {} {} {} {} {}
EC Number201-136-5
Chemical Name Translation3,3-二(氯甲基)氧杂环丁烷
Wiswesser Line NotationT4OTJ C1G C1G
Beilstein Registry Number0103354
LabNetwork Molecule IDLN00171930
Canonical SMILESClCC1(CCl)COC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 4ring; ether; 1fragment

相关文献及参考

  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
WGK Germany3
RTECSRQ6826000
Packing GroupIII
Hazard Codes Xn T+
Hazard Class6.1(b)
UN Number 2810
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R26 Very toxic by inhalation 吸入极毒
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Signal word Warning
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 8(7),31,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 600 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   FATOBP Farmakologiya i Toksikologiya (Kiev).  Pharmacology and Toxicology.
   (Kievskii Nauchno- Issledovatel'skii Institut Farmakologii i Toksikologii,
   Kiev, USSR)  No.1-    1964-  Volume(issue)/page/year: 5,157,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   FATOBP Farmakologiya i Toksikologiya (Kiev).  Pharmacology and Toxicology.
   (Kievskii Nauchno- Issledovatel'skii Institut Farmakologii i Toksikologii,
   Kiev, USSR)  No.1-    1964-  Volume(issue)/page/year: 5,157,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 545 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 可燃性危险特性:可燃; 燃烧产生有毒氯化物烟雾
  • 毒性分级:高毒
  • MOL 文件:78-71-7.mol
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 急性毒性:口服-大鼠 LD50: 600 毫克/公斤; 口服-小鼠 LD50: 420 毫克/公斤
  • 类别:有毒物品

系列性分类


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