Pentyl Nitrite 亚硝酸正戊酯

CAS 463-04-7 MFCD00036132

化学结构图

463-04-7
SMILES: CCCCCON=O

化学属性

Mol. FormulaC5H11NO2
Mol. Weight117.15
Refractive index1.3880 to 1.3910
Density0.88
Flash Point-18°C(lit.)
Boiling Point104°C(lit.)
Solubility微溶于水,溶于乙醇、乙醚、苯、丙酮等多数有机溶剂。

别名和识别编码

Chemical NamePentyl Nitrite
MDL NumberMFCD00036132
Synonym n-Amylnitrit 亚硝酸戊酯 1-Nitropentane Nitrous acid amyl ester Salpetrigsäurepentylester Pentyl alcohol, nitrite Pentyl nitrite Pentylnitrit n-Pentylnitrit Nitrousacid,pentylester Salpetrigsäure-n-pentylester 亚硝酸正戊酯 PENTYL NITRITE nitrousacidpentylester N-PENTYL NITRITE nitrous acid pentyl ester N-PENTYL NITRITE 97+% Amyl nitrite itramyl pentylalcohol,nitrite n-pentyl nitrite N-AMYL NITRITE AMYL NITRITE TERT-NITROOCTANE Nitramyl n-Amyl nitrite N-Phenyl nitrile 1-(Nitrosooxy)pentane
Reaxys-RN1701241
CAS Number463-04-7
Beilstein Registry Number1(4)1644
PubChem Substance ID87562079
EC Number207-332-7
Chemical Name Translation亚硝酸正戊酯
Wiswesser Line NotationONO5
LabNetwork Molecule IDLN00194151
InChIInChI=1S/C5H11NO2/c1-2-3-4-5-8-6-7/h2-5H2,1H3
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分类

  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Organic Nitrates/Nitrites
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: IV/6 Title: Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch. Editor: Madelung, O. Source: Landolt-Börnstein, New Series Volume: IV/6 Year: 1991 Keyword: organic compounds; dielectric constant; liquids; mixtures ISBN: 3-540-54417-8 ISBN: 978-3-540-54417-3 Internet Resource: DOI:10.1007/b44266 RefComment: VIII, 521 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical

安全信息

RTECSRA1140000
UN Number 1113
Signal word
Precautionary statements
  • P304+P340+P312
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P303+P361+P353
  • P301+P312+P330
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P403+P235
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P241+P242+P243
Storage condition 0-10 0-10°C Refrigerator
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302+H332
Packing GroupII
Hazard Class3
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R11 Highly flammable 非常易燃
GHS Symbol
WGK Germany3
Hazard Codes
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   HDTU** "Pharmakologische Prufung von Analgetika, Dissertation," Herrlen, G.,
   Pharmakologischen Institut der Universitat Tubingen, Fed. Rep. Ger., 1933 
   Volume(issue)/page/year: -,-,1933

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale.  (Casa
   Editrice Idelson, Via A. de Gasperi, 55, 80133 Naples, Italy)  V.2- 1927- 
   Volume(issue)/page/year: 56,816,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

其他信息

  • 用途一:用于有机合成及香料的制备,也用作氧化剂、溶剂
  • 方法一:由正戊醇与亚硝酸钠反应而得。将亚硝酸钠溶液、盐酸、正戊醇分别打入高位槽中,管道外面用冰水冷却。然后以相同速度慢慢分别滴入盐酸及亚硝酸钠溶液。产生气泡后,从管道顶部慢慢滴加正戊醇,以生成亚硝酸正戊酯。经洗涤,干燥,减压蒸馏而得成品。
  • 储运特性:库房通风低温干燥; 与氧化剂, 还原剂分开存放
  • 外观性质:淡黄色液体,具有强烈的水果气味。
  • 上游原料:1-戊醇
  • 图谱信息:亚硝酸正戊酯(463-04-7)核磁图( 13 CNMR) 亚硝酸正戊酯(463-04-7)红外图谱(IR2) 亚硝酸正戊酯(463-04-7)红外图谱(IR1) 亚硝酸正戊酯(463-04-7)质谱(MS)
  • 毒性分级:低毒
  • 可燃性危险特性:明火, 高温,遇氧化剂即燃; 燃烧产生有毒氮氧化物烟雾
  • MOL 文件:463-04-7.mol
  • 亚硝酸正戊酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0455 亚硝酸戊酯 Amyl Nitrite 500ML 5780元 2014/06/02 A0455 亚硝酸戊酯 Amyl Nitrite 25ML 868元
  • MSDS 信息:亚硝酸正戊酯(463-04-7).msds
  • 爆炸物危险特性:为氧化剂; 其蒸汽遇热爆炸
  • 用途二:有于有机合成。
  • 下游产品:香芹酮 --> 2-氨基-Α-甲基-(1,1'-联苯)-4-乙腈
  • 海关编码:29209085
  • 灭火剂:醇泡沫
  • 类别:易燃液体
  • 急性毒性:皮下-小鼠 LDL0:30000 毫克/公斤
  • TCI Shanghai:亚硝酸戊酯 Amyl Nitrite,>;95.0%(GC)(463-04-7)

系列性分类


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