4-Methoxyphenylboronic Acid 对甲氧基苯硼酸

CAS 5720-07-0 MFCD00039139

化学结构图

5720-07-0
SMILES: COc1ccc(B(O)O)cc1

化学属性

Density1.422
TSCANo
Mol. FormulaC7H9BO3
Mol. Weight151.96
Appearance white to off-white pwdr.
Melting Point204-206°C
Boiling Point306.8°C at 760 mmHg

别名和识别编码

Chemical Name4-Methoxyphenylboronic Acid
Alfabeta NameMETHOXYPHENYLBORONICACID 4-
Synonym 4-Methoxyphenylboronic acid {LY} 4-Methoxyphenylboronic acid {} {LY} 4-Methoxyphenylboronic acid {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Methoxyphenylboronic acid {} {} {} {} {} {} {} {}
Beilstein Registry Number2936912
PubChem Substance ID201262
EC Number250-023-7
Chemical Name Translation对甲氧基苯硼酸
Reaxys-RN2936912
InChIKeyVOAAEKKFGLPLLU-UHFFFAOYSA-N
Wiswesser Line NotationQBQR DO1
LabNetwork Molecule IDLN00115930
InChIInChI=1S/C7H9BO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3
MDL NumberMFCD00039139
CAS Number5720-07-0
Canonical SMILESCOC1=CC=C(B(O)O)C=C1
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Pandiarajan, D.; Ramesh, R., Suzuki-Miyaura cross-coupling reaction of aryl bromides catalyzed by palladium(II) pyridoxal hydrazone complexes J. Organomet. Chem. 708-709 , 18-24, (2012)
  • 2. Lv, T.; et al., Pd-catalyzed direct arylation of phenylpyrazole: Synthesis of fipronil derivatives with aryl boronic acids promoted by a stoichiometric amount of NIS J. Fluor. Chem. 137 , 44-49, (2012)
  • 3. Sartori, G.; et al. , Highly effective synthesis of C-5-substituted 2'-deoxyuridine using Suzuki-Miyaura cross-coupling in water Synthesis 5th ed., 44 , 767-772, (2012)
  • 4. Yao, B.; et al. , Palladium-Catalyzed Heck-Type Reactions of Allylic Esters with Arylboronic Acids or Potassium Aryltrifluoroborates Adv. Synth. Catal. 6th ed., 354 , 1069-1076, (2012)
  • 5. Inamoto, K.; et al. , Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones Chem. Commun. 36th ed., 48 , 4332-4334, (2012) 摘要
  • 6. Qi, Q.; et al. , Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature J. Am. Chem. Soc. 15th ed., 134 , 6548-6551, (2012) 摘要
  • 7. Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
  • 8. Xue, F.; et al. , Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin-Sulfoxide Ligands J. Org. Chem. 7th ed., 77 , 3071-3081, (2012) 摘要
  • 9. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
  • 10. Sindhuja, E.; Ramesh, R.; Liu, Y., Palladium(II) thiocarboxamide complexes: synthe

安全信息

Warnings IRRITANT
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
RTECSCY8975000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00062

Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Monosubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkyl
  1. Functional Group 官能团索引
  2. boronic acid
  1. Boronic Acid and Ester
  2. Boron

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