3,3'-Dichlorobenzidine dihydrochloride 3,3-二氯联苯胺盐酸盐

CAS 612-83-9 MFCD00040388

化学结构图

612-83-9
SMILES: Cl.Cl.Nc1ccc(-c2ccc(N)c(Cl)c2)cc1Cl

化学属性

Mol. FormulaC12H12Cl4N2
Mol. Weight326
Solubility<0.1 G/100 ML AT 21.5 ºC
Melting Point132~137℃

别名和识别编码

Chemical Name3,3'-Dichlorobenzidine dihydrochloride
MDL NumberMFCD00040388
CAS Number612-83-9
PubChem Substance ID11933
EC Number210-323-0
Synonym [1,1'-Biphenyl]-4,4'-diamine, 3,3'-dichloro-, dihydrochloride 3,3’-dichloro-benzidindihydrochloride 3,3-DICHLOROBENZIDINE DIHYDROCHLORIDE 3,3’-二氯-4,4’-联苯二胺,盐酸盐 3，3′-二氯联苯胺盐酸盐 3,3-DICHLOROBENZIDINE DIHYD 3,3'-DICHLOROBENZIDINE 2HCL 盐酸二氯联苯胺 3,3'-Dichloro(1,1'-biphenyl)-4,4'-diamine dihydrochloride 4,4'-DIAMINO-3,3'-DICHLOROBIPHENYLDIHYDROCHLORIDE 3,3'-二氯联苯胺盐酸盐 3,3′-二氯联苯胺 二盐酸盐 3, 3''-DICHLOROBENZIDINE DIHYDROCHLORIDE, 99.5% 3,3'-Dichloro-4,4'-diaminobiphenyl dihydrochloride 3,3'-Dichlorobenzidine dihydrochloride 3,3'-Dichloro Benzidene Dihydrochloride 3,3'-DICHLOROBENZIDINE DIHYDROCHLORIDE 二氯联苯胺盐 3,3'-DICHLORO-4,4'-DIAMINODIPHENYL DIHYDROCHLORIDE 4-(4-Amino-3-chlorophenyl)-2-chloroaniline dihydrochloride 3,3'-二氯-4,4'-联苯二胺//联苯胺 3,3'-Dichlorobenzidine HCl 1’-biphenyl]-4,4’-diamine,3,3’-dichloro-[dihydrochloride 二氯聯苯胺 3,3'-Dichlorobenzidine dihydrochloride 1’-biphenyl)-4,4’-diamine,3,3’-dichloro-(dihydrochloride (1,1'-Biphenyl)-4,4'-diamine, 3,3'-dichloro-, dihydrochloride DCB盐酸盐 3,3'-二氯联苯胺 3,3'-Dichlorobenzidine·2hydrochloride 3,3'-DICHLORO-4,4'-BIPHENYLDIAMINE DIHYDROCHLORIDE
Chemical Name Translation3,3-二氯联苯胺盐酸盐
Wiswesser Line NotationZR BG D- 2 &GH &GH
LabNetwork Molecule IDLN01747510
InChIInChI=1S/C12H10Cl2N2.2ClH/c13-9-5-7(1-3-11(9)15)8-2-4-12(16)10(14)6-8;;/h1-6H,15-16H2;2*1H
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分类

  • {SNA} Analytical Standards, Chromatography, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱
  • {SNA} Cancer Research, Carcinogens
  • {SNA} Analytical Standards, Food and Cosmetic Component Standards, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱
  • {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009)

产品应用

  • 工业致癌物质，诱导实验室动物的肝瘤和膀胱瘤。

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P318
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P333+P313
  • P337+P313
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H312 Harmful in contact with skin 皮肤接触有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H350 May cause cancer 可能致癌
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
RTECSDD0550000
Signal word Danger
Hazard Codes T,N T;N
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R50/53
  • R45 May cause cancer 可能致癌
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
UN Number UN 3077 9/PG 3 3077
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3820 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,211,1969

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

Restrict 危险品

其他信息

  • 用途一:用作分析试剂和染料中间体
  • Sigma Aldrich:612-83-9(sigmaaldrich)
  • MSDS 信息:3,3'-二氯联苯胺盐酸盐，盐酸二氯联苯胺(612-83-9).msds
  • MOL 文件:612-83-9.mol
  • 用途二:用于生产染料、颜料及油墨
  • 上游原料:氢氧化钠 --> 甲醇 --> 水合肼 --> 水合肼 --> 1,4-萘醌
  • 外观性质:针状结晶。
  • 下游产品:2,2'-(3,3'-二氯-1,1'-联苯-4,4'-双偶氮)双(N-苯基-3-氧代-丁酰胺)

系列性分类

  1. Life Science 生命科学
  2. Cancer Research
  3. Carcinogens - Cancer Research
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环

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