1-Bromo-4-(trifluoromethoxy)benzene 1-溴-4-三氟甲氧基苯

CAS 407-14-7 MFCD00040834

化学结构图

407-14-7
SMILES: FC(F)(F)Oc1ccc(Br)cc1

化学属性

Mol. FormulaC7H4BrF3O
Mol. Weight241
Boiling Point80
Refractive index1.4600 to 1.4620
Density1.622
Flash Point67°C(lit.)
TSCANo
Appearance 本品为无色液体，b.p.80℃/6.67 kpa，n 1.4610，相对密度 1.6220，f.p.225℉(107℃)，不溶于水，溶于苯、甲苯。 D 20

别名和识别编码

Chemical Name1-Bromo-4-(trifluoromethoxy)benzene
CAS Number407-14-7
Alfabeta NameBROMOTRIFLUOROMETHOXYBENZENE 14()---
MDL NumberMFCD00040834
PubChem Substance ID521008
EC Number206-979-2
Beilstein Registry Number2046332
Reaxys-RN2046332
Synonym (Trifluoromethoxy)bromobenzene 1-Brom-4-(trifluormethoxy)-benzol 1-bromo-4-(trifluoromethoxy)benzene 1-溴-4-(三氟甲氧基)苯 1-溴-4-三氟甲氧基苯 4-(TRIFLUOROMETHOXY)BROMOBENZENE 4-(Trifluoromethoxy)bromobenzene 4-(trifluoromethoxy)bromobenzene,1-bromo-4-(trifluoromethoxy)benzene 4-Bromophenyl(trifluoromethyl) ether 4-Bromozbenzotrifluoride 4-Trifluoromethoxybromobenzene 4-三氟甲氧基溴苯 4-溴三氟甲氧基苯 p-Bromophenyl trifluoromethyl ether Benzene, 1-bromo-4-(trifluoromethoxy)- P-BROMOTRIFLUOROMETHOXYBENZENE P-Bromotrifluoromethoxybenzen TIMTEC-BB SBB006606 对三氟甲氧基溴苯 对溴三氟甲氧基苯
Chemical Name Translation1-溴-4-三氟甲氧基苯
InChIKeySEAOBYFQWJFORM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00001023
InChIInChI=1S/C7H4BrF3O/c8-5-1-3-6(4-2-5)12-7(9,10)11/h1-4H
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分类

  • {SNA} Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • {Chemicalbook} 农药中间体: 植物生长调节剂中间体
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Building Blocks, C2 to C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • FT-IR 2 (2), 1786:D / FT-NMR 1 (2), 187:B / RegBook 1 (1), 1233:I / Structure Index 1 , 188:B:9
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany1
Hazard Codes 9
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P342+P311
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R51/53
Packing GroupIII
UN Number 3082

其他信息

  • 方法一:其制备方法是以4-溴苯氧基硫代羧酰氯与MoF 3 反应而制得产品。
  • Acros Organics:1-溴-4-三氟甲氧基苯 1-Bromo-4-(trifluoromethoxy)benzene, 98%(407-14-7)
  • 图谱信息:1-溴-4-三氟甲氧基苯(407-14-7)核磁图( 13 CNMR) 1-溴-4-三氟甲氧基苯(407-14-7)红外图谱(IR1) 1-溴-4-三氟甲氧基苯(407-14-7)质谱(MS) 1-溴-4-三氟甲氧基苯(407-14-7)核磁图( 1 HNMR)
  • Alfa Aesar:1-溴-4-(三氟甲氧基)苯,98% 1-Bromo-4-(trifluoromethoxy)benzene, 98%(407-14-7)
  • Sigma Aldrich:407-14-7(sigmaaldrich)
  • Hazard Note:Irritant
  • TCI Shanghai:1-溴-4-三氟甲氧基苯 1-Bromo-4-(trifluoromethoxy)benzene,>;97.0%(GC)(407-14-7)
  • 1-溴-4-三氟甲氧基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1772 1-溴-4-(三氟甲氧基)苯 1-Bromo-4-(trifluoromethoxy)benzene 5G 302元 2014/06/02 B1772 1-溴-4-(三氟甲氧基)苯 1-Bromo-4-(trifluoromethoxy)benzene 25G 917元 2010/06/21 TL00418FA 1-溴-4-三氟甲氧基苯 1-bromo-4-(trifluoromethoxy)benzene 100 GR 990元
  • 上游原料:溴苯
  • MOL 文件:407-14-7.mol
  • 用途二:1-溴-4-(三氟甲氧基)苯是植物生长调节剂呋嘧醇的中间体。
  • 海关编码:29093090
  • MSDS 信息:1-Bromo-4-(trifluoromethoxy)benzene(407-14-7).msds
  • 用途一:用作农药、医药中间体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C2 to C8 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides
  1. Materials Science 材料科学
  2. Building Blocks for Liquid Crystals

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