Tris[3,5-Bis(Trifluoromethyl)Phenyl]Phosphine 三[3,5-二(三氟甲基)苯基]膦
CAS 175136-62-6 MFCD00042428
化学结构图
SMILES: FC(F)(F)C1=CC(=CC(=C1)P(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C(F)(F)F
化学属性
| Melting Point | 99.0 to 103.0 deg-C |
|---|---|
| TSCA | No |
| Boiling Point | 130°C/0.5mmHg(lit.) |
| Flash Point | 128-130°C/0.5mm |
| Mol. Formula | C24H9F18P |
| Appearance | brown solid |
| Mol. Weight | 670 |
别名和识别编码
| Chemical Name | Tris[3,5-Bis(Trifluoromethyl)Phenyl]Phosphine |
|---|---|
| PubChem Substance ID | 253662549 |
| Beilstein Registry Number | 6556841 |
| Synonym | Tris3,5-bis(trifluoromethyl)phenylüphosphine, 94% 三[3,4-双(三氟甲基)苯基]膦 Tris[3,5-bis(trifluoromethyl)phenyl]phosphine97% TRIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE 97% TRIS[3,5-DI(TRIFLUOROMETHYL)PHENYL]PHOSPHINE TRIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE 三[3,5-二(三氟甲基)苯基]膦 三[3，5-二(三氟甲基）苯基]磷化氢 三[N,N-双(三甲基硅烷)胺]磷 TRI[3,5-DI(TRIFLUOROMETHYL)PHENYL]PHOSPHINE TRIS[BIS(3,5-TRIFLUOROMETHYL)PHENYL]PHOSPHINE |
| Chemical Name Translation | 三[3,5-二(三氟甲基)苯基]膦 |
| Reaxys-RN | 6556841 |
| LabNetwork Molecule ID | LN01109849 |
| MDL Number | MFCD00042428 |
| CAS Number | 175136-62-6 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
相关文献及参考
- In a study of coupling reactions in supercritical CO2, catalyzed by Tris(dibenzylideneacetone)dipalladium(0), 12760, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tri(2-furyl)phosphine, L13329, Tris(pentafluorophenyl)phosphine, L02748
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P337+P313
- P302+P352+P332+P313+P362+P364
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- Acros Organics:Tri[3,5-di(trifluoromethyl)phenyl]phosphine, 90%(175136-62-6)
- F:10-23
- Hazard Note:Irritant/Air Sensitive/Keep under nitrogen
- MOL 文件:175136-62-6.mol
- color:yellow-brown
- Sigma Aldrich:175136-62-6(sigmaaldrich)
- 敏感性:Air Sensitive
- Alfa Aesar:三［3,4-双（三氟甲基）苯基］膦,94% Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%(175136-62-6)
- 三[3，5-二(三氟甲基）苯基]磷化氢价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 CD03352EA 三[3，5-二(三氟甲基）苯基]磷化氢 tri[3,5-di(trifluoromethyl)phenyl]phosphine 10 GR 7005元 2010/05/25 L06941 三［3,4-双（三氟甲基）苯基］膦, 94% Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94% 250mg 419元 2010/05/25 L06941 三［3,4-双（三氟甲基）苯基］膦, 94% Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94% 1g 1267元
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