Bis(Dimethyl(Phenyl)Silyl)Amine 双(二甲基(苯基)硅烷基)胺

CAS 3449-26-1 MFCD00042916

化学结构图

3449-26-1
SMILES: C[Si](C)(N[Si](C)(C)c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC16H23NSi2
Mol. Weight285.53
Refractive index1.5350 to 1.5390
Boiling Point96-100
Density0.985
Flash Point>110°C

别名和识别编码

Chemical NameBis(Dimethyl(Phenyl)Silyl)Amine
Synonym Bis(dimethyl(phenyl)silyl)amine {LY} Bis(dimethyl(phenyl)silyl)amine {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(dimethyl(phenyl)silyl)amine {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00042916
CAS Number3449-26-1
PubChem Substance ID76988
EC Number222-372-5
Beilstein Registry Number2738118
Reaxys-RN2738118
Chemical Name Translation双(二甲基(苯基)硅烷基)胺
InChIKeyHIMXYMYMHUAZLW-UHFFFAOYSA-N
LabNetwork Molecule IDLN01741640
InChIInChI=1S/C16H23NSi2/c1-18(2,15-11-7-5-8-12-15)17-19(3,4)16-13-9-6-10-14-16/h5-14,17H,1-4H3
Canonical SMILESC[Si](C)(C1=CC=CC=C1)N[Si](C)(C)C2=CC=CC=C2
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Deactivating Glassware and Chromatographic Supports, Reagents for Silylation, Silylation Reagents
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Silazanes
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Silylation - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silazanes - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silazanes - Organosilicon
  1. Analytical & Chromatography 分析化学与色谱
  2. GC Derivatizing Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Fluka Reagents

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