Allylpalladium(II) Chloride Dimer 氯化烯丙基钯(II)二聚物

CAS 12012-95-2 MFCD00044874

化学结构图

12012-95-2
SMILES: C=C[CH2-].C=C[CH2-].Cl[Pd+].Cl[Pd+]

化学属性

SolubilityVery soluble in dichloromethane and dichloroethane. Slightly soluble in toluene, insoluble in water
TSCANo
Density6.68
Mol. FormulaC6H10Cl2Pd2
Stabilityair sensitive, store cold
Appearance yellow solid yellow xtl.
Mol. Weight365.86
Melting Point120°C dec.
pH:A

别名和识别编码

Chemical NameAllylpalladium(II) Chloride Dimer
Synonym 氯化烯丙基钯(II)二聚物 Bis(allyl)dichloropalladium Allyl palladium chloride dimer Diallyldichlorodipalladium 二(烯丙基)二氯二钯(II) Bis(allylchloropalladium) Bis(allyl)dichlorodipalladium 烯丙基氯化钯(II)二聚体，二(烯丙基)二氯二钯(II) 氯化烯丙基钯二聚物 烯丙基氯化钯二聚物 ChemDose™ 片 [PdCl(C3H5)]2 Allylpalladium(II) chloride dimer Bis(allyl)dichlorodipalladium(II) Allylchloropalladium dimer Bis(allyl)dichlorodipalladium Bis(allyl)dichloropalladium Bis(allylchloropalladium) Diallyldichlorodipalladium [PdCl(C3H5)]2 [PdCl(allyl)]2 烯丙基氯化钯(II)二聚体 Allylchloropalladium dimer [PdCl(allyl)]2
EC Number234-579-8
Beilstein Registry Number4124623
PubChem Substance ID61538
Chemical Name Translation氯化烯丙基钯(II)二聚物
Wiswesser Line Notation2U1-PD-G 2
InChIKeyTWKVUTXHANJYGH-UHFFFAOYSA-L
LabNetwork Molecule IDLN00238817
InChIInChI=1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q2*-1;;;2*+2/p-2
MDL NumberMFCD00044874
CAS Number12012-95-2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
  • {SNA} 12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Greener Alternative Products, Homogeneous Pd Catalysts, Palladium
  • {SNA} ChemDose, Chemical Synthesis, Specialty Synthesis
  • {SNA} C-H Activation, Catalysis and Inorganic Chemi
  • {SNA} 12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Greener Alternative Products, Homogeneous Pd Catalysts, Palladium

产品应用

  • 1.烯烃对映选择性氢化硅烷化的预催化剂。
  • 2.环丙烯基醋酸盐不对称烷化和氨化的预催化剂。
  • 3.交叉耦联反应催化剂。
  • 4.二聚体可以用作Trost配体。
  • 5.作为高对映选择性烯丙基烷化和氨化的有用前体。
  • 6.烯烃甲锡烷基化催化剂。

相关文献及参考

  • Reacts with lithium enolates of esters, in the presence of CO and excess TMEDA, to give good yields of ɑ-cyclopropyl esters: Angew. Chem. Int. Ed., 31, 234 (1992).
  • Used in combination with a chiral diamine to effect displacement of a mesylate with Trimethyl­silyl­ azide, L00173, in the asymmetric synthesis of (+)-pancratistin: J. Am. Chem. Soc., 117, 10143 (1995).

安全信息

RTECSRT3510000
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air & Moisture Sensitive 充氮密闭冷藏，置于阴凉干燥处。
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P332+P313
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P301+P312+P330
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H302+H312+H332
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn Xi

其他信息

  • 溶于氯仿、二氯甲烷，水中分解。对空气和潮湿敏感。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. ChemDose™ - Specialty Synthesis
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  4. Homogeneous Pd Catalysts - Palladium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  4. Homogeneous Pd Catalysts - Palladium
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Grignard Reagents & Alkyl Metals
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Palladium 钯催化剂
  5. Heterogeneous Pd Catalysts
  1. Catalysts
  2. Palladium
  1. Catalysts
  2. 96-4650 Palladium Kit
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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