Zirconium N-Butoxide 锆酸四丁酯

CAS 1071-76-7 MFCD00048765

化学结构图

1071-76-7
SMILES: CCCCO[Zr](OCCCC)(OCCCC)OCCCC

化学属性

Refractive indexn20/D 1.466
TSCAYes
Boiling Point117 °C at 760 mmHg
Mol. FormulaC16H36O4Zr
Mol. Weight383.68
Density1.063
Flash Point38°C(lit.)
Appearance orange liq.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameZirconium N-Butoxide
Synonym Zirconium(IV)n-butoxide {LY} Zirconium(IV)n-butoxide {} {LY} Zirconium(IV)n-butoxide {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zirconium(IV)n-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zirconium(I
PubChem Substance ID160560
Beilstein Registry Number4132649
Reaxys-RN11535206
EC Number213-995-3
Chemical Name Translation锆酸四丁酯
InChIInChI=1S/4C4H9O.Zr/c4*1-2-3-4-5;/h4*2-4H2,1H3;/q4*-1;+4
MDL NumberMFCD00048765
CAS Number1071-76-7
Canonical SMILESCCCCO[Zr](OCCCC)(OCCCC)OCCCC
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Zirconium, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Zirconium

产品应用

  • 制备氧化锆聚晶体，该晶体覆在钢和铁合金的表面构成一层保护膜，有广阔的应用前景。

相关文献及参考

  • 1. DiMaggio, R. et al. Chem. Mater. 10 , 3839, (1998)
  • Di Maggio, R. et al. Chem. Mater. 10 , 3839, (1998)
  • FT-IR 2 (3), 4491:A / Structure Index 1 , 484:E:5

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P331+P330
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P333+P313
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger {} {} {} {} {} {} {} {} {} {TCI}
UN Number 1120 1993 UN 1993 3/PG 3 UN1120
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
  • R20 Harmful by inhalation 吸入有害
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fr
Packing GroupIII
Hazard Class3

其他信息

  • 锆酸四丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 Z0016 丁醇锆(IV) (约80%的1-丁醇溶液) Zirconium(IV) Butoxide (ca. 80% in 1-Butanol) 25G 144元 2014/06/02 Z0016 丁醇锆(IV) (约80%的1-丁醇溶液) Zirconium(IV) Butoxide (ca. 80% in 1-Butanol) 500G 807元 2010/05/25 B23317 正丁醇锆, 80% w/w in 1-butanol Zirconium n-butoxide, 80% w/w in 1-butanol 1kg 2618元
  • 用途一:制备氧化锆聚晶体，该晶体覆在钢和铁合金的表面构成一层保护膜，有广阔的应用前景。
  • MOL 文件:1071-76-7.mol
  • Alfa Aesar:正丁醇锆,80%w/win1-butanol Zirconium n-butoxide, 80% w/w in 1-butanol(1071-76-7)
  • 锆酸四丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 Z0016 丁醇锆(IV) (约80%的1-丁醇溶液) Zirconium(IV) Butoxide (ca. 80% in 1-Butanol) 25G 218元 2011/04/16 Z0016 丁醇锆(IV) (约80%的1-丁醇溶液) Zirconium(IV) Butoxide (ca. 80% in 1-Butanol) 500G 1250元 2010/05/25 B23317 正丁醇锆, 80% w/w in 1-butanol Zirconium n-butoxide, 80% w/w in 1-butanol 1kg 2618元
  • F:10-21
  • Sigma Aldrich:1071-76-7(sigmaaldrich)
  • TSCA:Yes
  • 锆酸四丁酯特性与用途:浅黄色透明粘稠液体，为锆酸四丁酯的丁醇溶液，溶于烃、醇、酯、醚类等有机溶剂，在空气中极易吸收水份，水解生成氢氧化锆。用于纳米二氧化锆（超微细二氧化锆）薄膜、粉末的制备，广泛用于各种电子屏幕的防眩光、防辐射、防静电功能及氧气的传感器和输导器等高科技新材料领域，用于耐高温的无机膜材料及精细陶瓷等。

系列性分类

  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Zirconium - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Zirconium 锆x
  1. Alkoxide
  2. Zirconium