(2-Carboxyethyl)Triphenylphosphonium Tribromide (2-羧乙基)三苯基三溴化鏻

CAS 55985-85-8 MFCD00051883

化学结构图

55985-85-8
SMILES: [Br-].OC(=O)CC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.BrBr

化学属性

Mol. FormulaHO2CCH2CH2P(C6H5)3Br3
Mol. Weight575.09
Melting Pointca 159° dec.
TSCANo

别名和识别编码

Chemical Name(2-Carboxyethyl)Triphenylphosphonium Tribromide
MDL NumberMFCD00051883
CAS Number55985-85-8
Beilstein Registry Number6262851
Chemical Name Translation(2-羧乙基)三苯基三溴化鏻
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相关文献及参考

  • Reagent for ɑ-bromination of ketones. Unsaturated ketones can be selectivelyɑ-brominated in high yield without bromination of the olefinic double bond: Tetrahedron Lett., 373 (1975); Synth. Commun., 19, 1091 (1989). See also 2-Pyrrolidinone hydrotribromide, L00177 for similar reagent.

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
UN Number UN3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive

系列性分类


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