1-(Triisopropylsilyl)-1H-Pyrrole 1-(三异丙基甲硅烷基)-1H-吡咯

CAS 87630-35-1 MFCD00054932

化学结构图

87630-35-1
SMILES: CC(C)[Si](C(C)C)(C(C)C)N1C=CC=C1

化学属性

Mol. FormulaC13H25NSi
Mol. Weight223.44
Density0.904 g/mL at 25 °C(lit.)
Boiling Point78 °C/0.4 mmHg(lit.)
Refractive index1.4910 to 1.4930
Flash Point107°C(lit.)
TSCANo

别名和识别编码

Chemical Name1-(Triisopropylsilyl)-1H-Pyrrole
CAS Number87630-35-1
Alfabeta NameTRIISOPROPYLSILYLPYRROLE 1()-
MDL NumberMFCD00054932
Synonym N-(triisopropylsilyl)pyrrole 1-(三异丙基硅基)吡咯 1-(Triisopropylsilyl)pyrrole 1H-Pyrrole, 1-[tris(1-methylethyl)silyl]- TIPS-pyrrole 1-Triisopropylsilanyl-1H-pyrrole 1-(tris(1-methylethyl)silyl)-1H-pyrrole
PubChem Substance ID87577416
Beilstein Registry Number3540663
Chemical Name Translation1-(三异丙基甲硅烷基)-1H-吡咯
Reaxys-RN3540663
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分类

  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 5ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Pyrroles

相关文献及参考

  • Valuable intermediate in which the bulky TIPS group promotes regioselective 3-substitution. Bromination, nitration and base-catalyzed acylation all occur regioselectively at the 3-position: Tetrahedron Lett., 24, 3455 (1983). Metallating agents also attack at the 3-position: J. Org. Chem ., 55, 6317 (1990); 57, 1653 (1992). The silyl group is easily removed with F -, e.g. TBAF. For a review of synthesis of 3-substituted pyrroles, see: Synthesis, 353 (1985). Compare 1-(Phenyl­sulfonyl)­pyrrole, A11599.
  • Short: III/35C2

安全信息

Warnings IRRITANT
WGK Germany3
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R20 Harmful by inhalation 吸入有害
  • R36 Irritating to eyes 刺激眼睛
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Storage condition Moisture Sensitive
Hazard Codes Xn
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302+H332
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Warning
GHS Symbol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrroles 吡咯
  1. Materials Science 材料科学
  2. Reagents for Conducting Polymer Research

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