Chlordimeform 正己烷中杀虫脒溶液

CAS 6164-98-3 MFCD00055257

化学结构图

6164-98-3
SMILES: Cc1cc(Cl)ccc1N=CN(C)C

化学属性

Mol. FormulaC10H13ClN2
Mol. Weight196.70
Solubility微溶于水、苯、氯仿。
Density1.1
Refractive index1.558
Boiling Point163-165°C
Melting Point32°C

别名和识别编码

Chemical NameChlordimeform
Synonym 1-(2-Methyl-4-chlorophenyl)-3,3-dimethylformamidine Acaron C 8514 CHLORDIMEFORM CHLORPHENAMIDINE(R) Chlordimeform Chlordimeform emulsion(content>10%) Chlorfenamidine Chlorphenamidine Formamidine, N,N-dimethyl-N'-(2-methyl-4-chlorophenyl)- Fundal GLAECRON(R) Gal Galecron Methanimidamide, N'-(4-chlor N'-(2-Methyl-4-chlorophenyl)-N,N-dimethylformamidine N'-(4- N'-(4-chloro-2-methylphenyl)-N,N-dimethyl methanimidamide N'-(4-chloro-2-methylphenyl)-N,N-dimethylmethanimidamide N'2-(4-chloro-o-tolyl)-N'1,N'1-dimethylformamidine N' N'-(4-CHLORO-O-TOLYL)-N,N-DIMETHYL FORMAMIDINE N(sup 2)-(4-Chloro-o-tolyl)-N(sup 1),N(sup 1)-d
MDL NumberMFCD00055257
CAS Number6164-98-3
Beilstein Registry Number2088124
EC Number228-200-5
Chemical Name Translation正己烷中杀虫脒溶液
Merck Number13,2100
Wiswesser Line NotationGR C1 DNU1N1&1
PubChem Substance ID22544
InChIInChI=1S/C10H13ClN2/c1-8-6-9(11)4-5-10(8)12-7-13(2)3/h4-7H,1-3H3
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分类

  • {SNA} Acaricides, Alphabetic, Analytical Standards, Analytical/Chromatography, C, CH, Chromatography, Environmental Standards, Formamides, Insecticides, Method Specific, Oeko-Tex Standard 100, Pesticides, Pesticides & Metabolites, Pesticides Standards
  • {SNA} Acaricides,
  • {SNA} Acaricides, Analytical Standards, C, Food and Cosmetic Component Standards, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 农残和代谢标准品, 分析/色谱, 按照字母排序

产品应用

  • 有机氮杀虫剂。有良好的内吸作用，有较好的杀虫，杀螨效果。主要用于防治水稻螟虫，也可用于防治棉花红蜘蛛，红铃虫和果树红蜘蛛，介壳虫等。一般稀释为300-500倍喷雾。每亩田月用杀虫脒原药50g。杀虫脒代谢产物的毒性问题曾有争议，使用时应严格按照农业部门的规定。该品对蚕高毒，在蚕桑地区使用时应特别注意。不宜与碱性农药混用。

相关文献及参考

  • Short: EINECS
  • Short: IV/8A
  • Merck: 14,2085

安全信息

RTECSLQ4375000
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P316
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P308+P316
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P317
  • P337+P317
  • P361+P364
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
WGK Germany1
Signal word Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S22 Do not breathe dust 不要吸入粉尘；
Hazard Codes Xn,N
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R50/53
Storage condition 储存温度2-8°C 2-8°C
UN Number 2761
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6552 mg/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CHYCDW Zhonghua Yufangyixue Zazhi.  Chinese Journal of Preventive Medicine.
   (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep.
   China)  Beginning history not known.  Volume(issue)/page/year: 19,154,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 625 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College
   Science Pub., 1969  Volume(issue)/page/year: 5,43,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : >5800 mg/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A074,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 263 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   7,299,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Roden

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 225 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SPEADM Special Publication of the Entomological Society of America.  (4603
   Calvert Rd., College Park, MD 20740)  Volume(issue)/page/year: 78-1,21,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 5 ppm
REFERENCE :
   RSTUDV Rivista di Scienza e Technologia degli Alimenti e di Nutrizione
   Umana.  Review of Science and Technology of Food and Human Nutrition.
   (Bologna, Italy)  V.5-6, 1975-76.  Discontinued.  Volume(issue)/page/year:
   6,161,1976

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 11,184,1974

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 11,184,1974

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 10 ppb
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   25,148,1995

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 umol/plate
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 34,157,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1800 ug/kg
SEX/DURATION            : female 5-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 20,760,1978

其他信息

  • 杀虫脒价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80149480 杀虫脒;N-(2-甲基-4-氯苯基)-N′,N′-二; N′-(4-氯甲苯基)-N,N-二甲基甲; 氯苯脒; 杀螨螟; 杀螨脒; 克死螨; 杀螟螨 g 1250元
  • MOL 文件:6164-98-3.mol
  • 生产方法:杀虫脒有多种合成路线：（1）光气法；以100%杀虫脒计原料消耗定额：光气790kg/t、二甲基甲酰氯480kg/t、邻甲苯胺640kg/t、氯气410kg/t。（2）氧氯化磷法；（3）氯化亚砜法；（4）对甲苯磺酰氯法等等。
  • RTECS号:LQ4375000
  • 外观性质:白色结晶，有氨的气味。
  • 用途:有机氮杀虫剂。有良好的内吸作用，有较好的杀虫、杀螨效果。主要用于防治水稻螟虫，也可用于防治棉花红蜘蛛、红铃虫和果树红蜘蛛、介壳虫等。一般稀释为300-500倍喷雾。每亩田约用杀虫脒原药50g。杀虫脒代谢产物的毒性问题曾有争议，使用时应严格按照农业部门的规定。该品对蚕高毒，在蚕桑地区使用时应特别注意。不宜与碱性农药混用。
  • PackingGroup:III
  • HazardClass:6.1(b)
  • 20℃的蒸气压为0.047pa.20℃时在水中溶解度为250ppm，易溶于有机溶剂。商品为其盐酸盐水溶液。纯品杀虫脒盐酸盐，易溶于水，难溶于有机溶剂，在酸性溶液中稳定，中性溶液中易析出结晶，遇碱分解。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Acaricides - Pesticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CH - C
  1. Functional Group 官能团索引
  2. carboxylic acid amidine

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