Demeton-O 内吸磷-O

CAS 298-03-3 MFCD00055358

化学结构图

298-03-3
SMILES: CCSCCOP(=S)(OCC)OCC

化学属性

Mol. FormulaC8H19O3PS2
Mol. Weight258.36
Flash Point45 °C
Solubility易溶于甲苯、乙醇等。

别名和识别编码

Chemical NameDemeton-O
Synonym O,O-Diethyl-O-(2-ethylthioethyl)-thiophosphat {uni_hamburg} O,O-diethyl O-(2-(ethylthio)ethyl)phosphorothioate Ethanethiol, 2-(ethylthio)-, S-ester with O,O-diethyl phosphorodithioate Thiolmecaptophos Phosphorothioic acid, O,O-diethyl ester O-[2-(ethylthio)ethyl] ester Systox thiono Ethylthiometon phosphorothioic acid, O,O-diethyl O-[2-(ethylthio)ethyl]ester Bayer 8169 demeton O O,O-Diethyl O-(2-eththioethyl)phosphorothioate O,O-diethyl-O-2-ethylthoethylthiop demetonthione 内吸磷-O O,O-diethyl-O-2-ethylthoethyl phosphorothioate Diaethylthiophosphorsaeureester des aethylthioglykol demeton thiono Diethyl [2-(ethylthio)ethyl] phosphorothionate Phosphorothioic acid, O,O-diethyl O-[2-(ethylthio)ethyl] ester demeton-O O,O-Diethyl-2-ethylthio ethyl phosphorothioate Diethyl [2-(eththio)ethyl] thionophosphate Ethanol, 2-(ethylthio)-, O-ester with O,O-diethyl phosphorothioate Thiophosphorsäure-O,O-diethyl-O-(2-ethylthioethyl)ester demeton-O (ISO) O,O-Diethyl O-[2-(eththio)ethyl] phosphorothioate O,O-diethyl O-[2-(ethylthio)ethyl]phosphorothionate E 1059 Diethyl 2-(ethylthio)ethyl phosphorothionate Di-Septon O,O-diethyl O-[2-(ethylthio)ethyl]-thiophosphate demeton O (ISO) O,O-Diethyl O-[2-(ethylthio)ethyl] phosphorothionate Diethyl 2-eththioethyl thionophosphate O,O-Diethyl O-[2-(ethylthio)ethyl] phosphorothioate Phosphorothioic acid, O,O-diethyl O-[2-(ethylthio)ethyl ester O,O-diethyl O-2-ethylthioethyl phosphorothioate
MDL NumberMFCD00055358
PubChem Substance ID9273
EC Number206-053-8
CAS Number298-03-3
Wiswesser Line Notation2S2OPS&O2&O2
Beilstein Registry Number1709115
Chemical Name Translation内吸磷-O
LabNetwork Molecule IDLN04620845
InChIInChI=1S/C8H19O3PS2/c1-4-9-12(13,10-5-2)11-7-8-14-6-3/h4-8H2,1-3H3
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分类

  • {uni_hamburg} no charge; sulfide; 1fragment
  • {SA} Acaricides, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, D, DA - DH, Demeton metabolites, Environmental Standards, Insecticides, Metabolites, Organophorous, Pesticides, Pesticides & Metabolites
  • {SNA} Acaricides, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, D, DA - DH, Demeton metabolites, Environmental Standards, Insecticides, Metabolites, Organophorous,

相关文献及参考

  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSTF3125000
GHS Symbol
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
WGK Germany3
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes T+,N
Risk Statements
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R27/28 Very toxic in contact with skin and if swallowed 皮肤接触及吞食都有剧毒
Storage condition -20°C
UN Number 3018 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 15 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und
   Pharmakologie.  (Berlin, Ger.) V.110-253, 1925-66.  For publisher

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   58,152,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7500 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,161,1973

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 2(5),7,1958

TYPE OF TEST            : LDLo - Lowest published lethal dose

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - hamster
DOSE/DURATION           : 2 mg/kg
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   58,152,1986

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 100 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB80-133226

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 1000 ppm
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB80-133226

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 1000 ppm
REFERENCE :
   NTIS** National

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 5 ug/disc
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB80-133226

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 200 ug/plate
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB80-133226

其他信息

  • RTECS号:TF3125000
  • 外观性质:无色粘稠液体, 工业品为黄色液体, 有硫醇样臭味。
  • PackingGroup:I
  • HazardClass:6.1(a)
  • MOL 文件:298-03-3.mol

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Metabolites - Pesticides & Metabolites
  1. Functional Group 官能团索引
  2. thiophosphoric acid ester

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