2,2-DIMETHYLPROPYLMAGNESIUM CHLORIDE,1.0M SOLUTION IN DIETHYL ETHER 氯化新戊烷基镁

CAS 13132-23-5 MFCD00061550

化学结构图

13132-23-5
SMILES: CC(C)(C)C[Mg]Cl

化学属性

Mol. Formula(CH3)3CCH2MgCl
Mol. Weight130.90
Density0.952 g/mL at 25 °C
TSCANo

别名和识别编码

Chemical Name2,2-DIMETHYLPROPYLMAGNESIUM CHLORIDE,1.0M SOLUTION IN DIETHYL ETHER
Synonym 氯化新戊烷基镁 2,2-二甲基丙基氯化镁 溶液 2,2-Dimethylpropylmagnesium chloride
MDL NumberMFCD00061550
PubChem Substance ID329766702
CAS Number13132-23-5
Chemical Name Translation氯化新戊烷基镁
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分类

  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SA} Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents

安全信息

WGK Germany3
Precautionary statements
  • P402+P404
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P403+P235
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P305+P351+P338
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H302 Harmful if swallowed 吞食有害
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
GHS Symbol
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S8 Keep container dry 保持容器干燥；
Packing GroupII
UN Number UN3399
Risk Statements
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition Air & Moisture Sensitive
Hazard Codes F,C

系列性分类

  1. Organometallic Reagents - New Products for Chemical Synthesis
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents

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