Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] 二氯(五甲基环戊二烯基)合铑(III)二聚体
CAS 12354-85-7 MFCD00061552
化学结构图
SMILES: C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]1[C](C)[C](C)[C](C)[C]1C.Cl[Rh]Cl.Cl[Rh]Cl |^1:1,2,4,6,8,11,12,14,16,18|
化学属性
| TSCA | No |
|---|---|
| Melting Point | >300° |
| Mol. Formula | C20H30Cl4Rh2 |
| Appearance | red xtl. |
| Mol. Weight | 618 |
别名和识别编码
| Chemical Name | Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] |
|---|---|
| Synonym | Bis(dichloro(pentamethylcyclopentadienyl)rhodium) 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex Dichloro(pentamethylcyclopentadienyl)rhodium(III) Dimer 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex Bis(dichloro(pentamethylcyclopentadienyl)rhodium) Bis(pentamethylcyclopentadienylrhodium dichloride) Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium 二氯(五甲基环戊二烯基)合铑(III)二聚体 Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium Bis(pentamethylcyclopentadienylrhodium dichloride) Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer; Pentamethylcyclopentadienylrhodium(III) chloride dimer |
| PubChem Substance ID | 87560640 |
| Chemical Name Translation | 二氯(五甲基环戊二烯基)合铑(III)二聚体 |
| LabNetwork Molecule ID | LN02184022 |
| MDL Number | MFCD00061552 |
| CAS Number | 12354-85-7 |
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分类
- {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
- {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
- {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Rhodium Catalysts
- {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Catalysts,
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P304+P340+P312
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P332+P313
- P302+P352+P312+P362+P364
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P305+P351+P338+P337+P313
- P301+P312+P330
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P302+P350
- P337+P313
- H302+H312+H332
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S22 Do not breathe dust 不要吸入粉尘；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R42 May cause sensitisation by inhalation 吸入会产生过敏反应
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