Cis-1,4-Dichloro-2-Butene 顺-1,4-二氯-2-丁烯

CAS 1476-11-5 MFCD00062950

化学结构图

1476-11-5
SMILES: ClCC=CCCl

化学属性

Mol. FormulaC4H6Cl2
Mol. Weight125.00
Density1.188
Refractive index1.4870 to 1.4920
Boiling Point152 °C at 758 mmHg
Melting Point-48°C
Flash Point55°C(lit.)
TSCAYes
Stability对光线敏感，对湿度敏感
Appearance 顺式-1,4-二氯-2-丁烯(1476-11-5)为无色到浅黄色液体。熔点-48℃，沸点152℃ /101kPa。相对密度 1.88，折光率1.4884。

别名和识别编码

Chemical NameCis-1,4-Dichloro-2-Butene
CAS Number1476-11-5
Synonym (Z)-1,4-Dichlorobut-2-ene {LY} (Z)-1,4-Dichlorobut-2-ene {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Z)-1,4-Dichlorobut-2-ene
MDL NumberMFCD00062950
EC Number216-021-5
Beilstein Registry Number1(3)743
PubChem Substance ID6432115
Chemical Name Translation顺-1,4-二氯-2-丁烯
Reaxys-RN1719692
LabNetwork Molecule IDLN00196561
InChIInChI=1S/C4H6Cl2/c5-3-1-2-4-6/h1-2H,3-4H2/b2-1-
Canonical SMILESClC/C=C\CCl
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分类

  • Aliphatics
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: II/25C
  • Beilstein:1(3)743
  • Short: III/38B

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
Risk Statements
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R26 Very toxic by inhalation 吸入极毒
  • R45 May cause cancer 可能致癌
  • R50/53
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P403+P233
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P308+P311
  • P241+P242+P243
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H350 May cause cancer 可能致癌
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEM4900000
Packing GroupI
UN Number 3390 UN3390 3489
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
Hazard Codes T+,N
Hazard Class6.1/3, 8

其他信息

  • MOL 文件:1476-11-5.mol
  • TCI Shanghai:顺-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene,>;95.0%(GC)(1476-11-5)
  • Sigma Aldrich:1476-11-5(sigmaaldrich)
  • 下游产品:四氢呋喃 --> 1,4-丁二醇 --> 2-氯-1,3-丁二烯 --> 3-环戊烯-1-甲酸甲酯
  • F:8-21
  • 上游原料:乙醚 --> 氧氯化硫 --> 吡啶 --> 顺式-1,2-二羟甲基乙烯
  • 方法一:用丁烯二醇以氯化亚硫酰氯化制得。
  • 顺式-1,4-二氯-2-丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2449 顺-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene 5G 269元 2014/06/02 D2449 顺-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene 25G 722元 2010/06/21 187600250 顺式-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene 95% 25 ML 937元
  • MSDS 信息:cis-1,4-Dichloro-2-butene(1476-11-5).msds
  • 用途一:吡咯芬的合成。
  • 存储注意事项:氮气保护
  • 顺式-1,4-二氯-2-丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D2449 顺-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene 5G 270元 2011/04/16 D2449 顺-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene 25G 720元 2010/06/21 187600250 顺式-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene 95% 25 ML 937元
  • Alfa Aesar:顺-1,4-二氯-2-丁烯,95% cis-1,4-Dichloro-2-butene, 95%(1476-11-5)
  • Acros Organics:顺式-1,4-二氯-2-丁烯 cis-1,4-Dichloro-2-butene, 95%(1476-11-5)
  • 检测方法:GC,NMR

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl - Halogenated Hydrocarbons
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PA - PEN - P

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