D-glutamic acid D-谷氨酸

CAS 6893-26-1 MFCD00063112

化学结构图

6893-26-1
SMILES: N[C@H](CCC(=O)O)C(=O)O

化学属性

Mol. FormulaC5H9NO4
Mol. Weight147.13
Density1.409
Melting Point200-202°C
TSCAT
Solubility7 G/L (20 ºC)
Appearance D -30.5°(0.5-2mg/ml，6mol/L HCl)，LD 20 (人，静脉) 117mg/kg。 白色结晶或结晶性粉末；溶于水，微溶于乙醇，不溶于乙醚；比旋光度[α] 50
Boiling Point333.8°C at 760 mmHg

别名和识别编码

Chemical NameD-Glutamic Acid
CAS Number6893-26-1
Alfabeta NameGLUTAMICACID D-
MDL NumberMFCD00063112
EC Number230-000-8
Beilstein Registry Number1723800
Synonym D-Glutamic acid {LY} D-Glutamic acid {} {LY} D-Glutamic acid {} {} {LY} D-Glutamic acid {} {} {} {LY} D-Glutamic acid {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} D-Glutamic acid {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID23327
Merck Number4469
Reaxys-RN1723800
Chemical Name TranslationD-谷氨酸
LabNetwork Molecule IDLN00008526
InChIInChI=1S/C5H9NO4/c6-3(5(9)10)1-2-4(7)8/h3H,1-2,6H2,(H,7,8)(H,9,10)/t3-/m1/s1
Canonical SMILESN[C@H](CCC(O)=O)C(O)=O
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Resolution Reagents, Chiral Resolving Reagents, Excitatory Amino Acids, G, Neuroscience, Neurotransmission, Neurotransmitters, 生物活性小分子, 细胞信号转导和神经科学, 细胞生物学
  • {Chemicalbook} 生物化学品: 生化试剂: 氨基酸及其衍生物
  • {SNA} Asymmetric Synthesis, Chemical Syn
  • {SNA} Asymmetric Synthesis, Bioactive Small Molecules, Cell Biology, Cell Signaling and Neuroscience, Chemical Synthesis, Chiral Resolution Reagents, Chiral Resolving Reagents, Excitatory Amino Acids, G, Neuroscience, Neurotransmissio

产品应用

  • 氨基酸类药。

相关文献及参考

  • [2]. Chung SY, et al. IgE binding to peanut allergens is inhibited by combined D-aspartic and D-glutamic acids. Food Chem. 2015 Jan 1;166:248-53.
  • [3]. Wilson W, et al. The metabolism of D- and L- glutamic acid in the rat. J Biol Chem. 1961 Feb;236:365-9.
  • Merck: 14,4469
  • Merck: 14,4469 Beilstein:4(3)1549
  • [1]. Han H, et al. Changes in D-aspartic acid and D-glutamic acid levels in the tissues and physiological fluids of mice with various D-aspartate oxidase activities. J Pharm Biomed Anal. 2015 Dec 10;116:47-52.
  • [1]. Han H, et al. Changes in D-aspartic acid and D-glutamic acid levels in the tissues and physiological fluids of mice with various D-aspartate oxidase activities. J Pharm Biomed Anal. 2015 Dec 10;116:47-52.
  • [2]. Chung SY, et al. IgE binding to peanut allergens is inhibited by combined D-aspartic and D-glutamic acids. Food Chem. 2015 Jan 1;166:248-53.
  • [3]. Wilson W, et al. The metabolism of D- and L- glutamic acid i

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition 2-8°C {LY} 2-8°C Store at RT. {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
Hazard statements

其他信息

  • Acros Organics:D-谷氨酸/α-氨基戊二酸 D(-)-Glutamic acid, 99+%(6893-26-1)
  • MOL 文件:6893-26-1.mol
  • 下游产品:(R)-(-)-5-羟甲基-2-吡咯烷酮
  • D-谷氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp620011 D-谷氨酸;D-麸氨酸;D-麸质酸;D-2-氨基戊二酸 25g/瓶 150元 2011/04/16 G0057 D-谷氨酸 D-Glutamic Acid 250G 5860元 2011/04/16 G0057 D-谷氨酸 D-Glutamic Acid 25G 846元
  • Sigma Aldrich:6893-26-1(sigmaaldrich)
  • 图谱信息:D-谷氨酸(6893-26-1)质谱(MS) D-谷氨酸(6893-26-1)红外图谱(IR1) D-谷氨酸(6893-26-1)红外图谱(IR2)
  • 用途一:用于生化研究。
  • MSDS 信息:D-2-Aminoglutaric acid(6893-26-1).msds
  • 比旋光度:-31.3 ° (c=10, 2 N HCl)
  • 上游原料:DL-谷氨酸
  • TCI Shanghai:D-谷氨酸 D-Glutamic Acid,>;98.0%(T)(6893-26-1)
  • 用途二:氨基酸类药。
  • F:10
  • 谷氨酸的非天然异构体。水中溶解度:7 g/L (20°C)，实际上不溶于有机溶剂。
  • 参考质量标准:比旋光度[α] 20 D -31°--33°；纸层析合格。
  • 方法一:以乙酰-DL-谷氨酸为原料，经酰化酶处理后去L-型，精制、干燥得产品。
  • Alfa Aesar:D-谷氨酸,99+% D-Glutamic acid, 99+%(6893-26-1)

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Glutamic Acid - Amino Acid Derivatives
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Optical Resolution
  1. Medical Research Areas
  2. Metabolism
  3. Endogenous Metabolite  (内源性代谢物)

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