(R)-(+)-1-(1-Naphthyl)ethylamine (R)-1-(1-萘基)乙胺
CAS 3886-70-2 MFCD00064114
化学结构图
SMILES: C[C@@H](N)c1cccc2ccccc12
化学属性
| Mol. Formula | C12H13N |
|---|---|
| Mol. Weight | 171.24 |
| Refractive index | 1.6210 to 1.6240 |
| Boiling Point | 289.9°C at 760 mmHg |
| Density | 1.06 |
| Flash Point | >110°(230°F) |
| TSCA | Yes |
| Melting Point | 113°C |
别名和识别编码
| Chemical Name | (R)-(+)-1-(1-Naphthyl)ethylamine Cinacalcet Impurity A |
|---|---|
| CAS Number | 3886-70-2 |
| Alfabeta Name | NAPHTHYLETHYLAMINE ALPHAR+1(())---- |
| MDL Number | MFCD00064114 |
| Synonym | (+)-1-(1-Naphthyl)ethylamine {LY} (+)-1-(1-Naphthyl)ethylamine {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-1-(1-Naphthyl)ethylamine {} {} {} {} {} {} {} {} { |
| PubChem Substance ID | 2724264 |
| EC Number | 223-425-5 |
| Beilstein Registry Number | 2208025 |
| Chemical Name Translation | (R)-1-(1-萘基)乙胺 |
| Reaxys-RN | 2208024 |
| InChIKey | RTCUCQWIICFPOD-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00010216 |
| InChI | InChI=1S/C12H13N/c1-9(13)11-8-4-6-10-5-2-3-7-12(10)11/h2-9H,13H2,1H3/t9-/m1/s1 |
| Canonical SMILES | N[C@H](C)C1=CC=CC2=CC=CC=C12 |
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分类
- {SNA} Amines, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
- {SNA} Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC, 分析/色谱, 分析试剂
- {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC
产品应用
- 伯胺的绝对构型可用手性 (2-硝基苯基)脯氨酰胺和
- 1H NMR 测定。
相关文献及参考
- Beilstein:12(3)3110
安全信息
GHS Symbol
- H301 Toxic if swallowed 吞食有毒
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P316
- P301+P330+P331
- P302+P352
- P302+P361+P354
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P316
- P317
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
其他信息
- MSDS 信息:R-(+)-alpha-(1-Naphthyl)ethylamine(3886-70-2).msds
- (R)-1-(1-萘基)乙胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0482 (R)-(+)-1-(1-萘基)乙胺 (R)-(+)-1-(1-Naphthyl)ethylamine 5G 2250元 2014/06/02 N0482 (R)-(+)-1-(1-萘基)乙胺 (R)-(+)-1-(1-Naphthyl)ethylamine 1G 794元 2010/06/21 217800050 (R)-1-(1-萘基)乙胺 (R)-(+)-alpha-(1-Naphthyl)ethylamine 99+% 5 GR 1908元
- 敏感性:Air Sensitive
- 上游原料:1-萘甲醛 --> D-苯甘氨醇
- color:brown
- 下游产品:1R,3R-反式菊酸
- F:10-34
- Acros Organics:(R)-(+)-alpha-1-萘乙胺 (R)-(+)-alpha-(1-Naphthyl)ethylamine, 99+%(3886-70-2)
- Sigma Aldrich:3886-70-2(sigmaaldrich)
- 比旋光度:60 ° (c=2, CH3OH)
- Alfa Aesar:(R)-(+)-1-(1-萘基）乙胺,ChiPros99+%,ee98+% (R)-(+)-1-(1-Naphthyl)ethylamine, ChiPros 99+%, ee 98+%(3886-70-2)
- MOL 文件:3886-70-2.mol
- TCI Shanghai:(R)-(+)-1-(1-萘)乙胺 (R)-(+)-1-(1-Naphthyl)ethylamine,>;99.0%(GC)(3886-70-2)
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