L-Hydroxyproline L-羟基脯氨酸
CAS 51-35-4 MFCD00064320
化学结构图
SMILES: O=C(O)[C@@H]1C[C@@H](O)CN1
化学属性
| Mol. Formula | C5H9NO3 |
|---|---|
| Mol. Weight | 131.13 |
| Density | 1.395 |
| Melting Point | 273 |
| TSCA | Yes |
| Solubility | Soluble in water. |
别名和识别编码
| Chemical Name | L-Hydroxyproline |
|---|---|
| CAS Number | 51-35-4 |
| Alfabeta Name | HYDROXYPYRROLIDINECARBOXYLICACID SR2442()----, |
| MDL Number | MFCD00064320 |
| Synonym | 4-Hydroxyproline Hydroxy-L-proline 反-4-羟基-L-脯氨酸;反式-4-羟基-L-脯氨酸;L-4-羟基脯氨酸;L-羟脯氨酸 Hydroxyproline L-羟基脯氨酸 (2S,4R)-(-)-4-Hydroxypyrrolidine-2-carboxylic acid trans-Hydroxyproline (2S,4R)-4-羟基吡咯烷-2-羧酸 4-Hydroxyproline Hydroxyproline Hyp Hyp (2S,4R)-4-羟基吡咯烷-2-羧酸 (2S,4R)-4-Hydroxypyrrolidine-2-carboxylic acid L-4-Hydroxyproline 反-4-羟基-L-脯氨酸;反式-4-羟基-L-脯氨酸;L-4-羟基脯氨酸 trans-L-Hydroxyproline L-羟脯氨酸 反式-4-羟基-L-脯氨酸 (2S,4R)-4-羟基吡咯烷-2-羧酸 Hyp 反-4-羟基-L-脯氨酸, 99+% |
| EC Number | 200-091-9 |
| Beilstein Registry Number | 22(3/4)2047 |
| PubChem Substance ID | 87570719 |
| Merck Number | 4840 |
| Chemical Name Translation | L-羟基脯氨酸 |
| Reaxys-RN | 471933 |
| LabNetwork Molecule ID | LN00141965 |
| InChI | InChI=1S/C5H9NO3/c7-3-1-4(5(8)9)6-2-3/h3-4,6-7H,1-2H2,(H,8,9)/t3-,4+/m1/s1 |
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分类
- {SNA} A - H, Aloe Vera, Amino Acids, Chemical Biology, Chemical Synthesis, Modified Amino Acids, Panax ginseng, Peptide Chemistry, Phytochemicals by Plant (Food/Spice/Herb), Proline Derivatives, Unnatural Amino Acids & Derivatives, 生化试剂, 细胞生物学, 营养研究
- {SNA} Aloe Vera, Amino Acid, Amino Acids, Amino Acids and Vitamins, Chemical Biology, Chemical Synthesis, Panax ginseng, Peptide Chemistry, Phytochemicals by Plant (Food/Spice/Herb), Proline Derivatives, Unnatural Amino Acids & Derivatives,
- {SNA} Aloe Vera,
产品应用
- A versatile reagent for the synthesis of neuroexcitatory kainoids and antifungal echinocandins.
相关文献及参考
- Chiral precursor for a wide variety of synthetic targets. For discussion of some examples, see: Tetrahedron, 52, 13803 (1996).
- Merck: 14,4840
- Merck: 14,4840 Beilstein:22(3/4)2047
- [1]. Yi Y, et al. Biosynthesis of trans-4-hydroxyproline by recombinant strains of Corynebacterium glutamicum and Escherichia coli . BMC Biotechnol. 2014 May 19;14:44.
安全信息
GHS Symbol
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Human Lymphocyte DOSE/DURATION : 10 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 372,75,1996
其他信息
- Trans-4-Hydroxy-L-proline is a versatile reagent for the synthesis of neuroexcitatory kainoids and antifungal echinocandins. Also employed in the synthesis of chiral ligands for enantioselective ethylation of aldehydes. trans-4-Hydroxy-L-proline is a natural constituent of animal structural proteins such as collagen and elastin.
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