Tris(1,1,1,2,2,3,3-Heptafluoro-7,7-Dimethyl-4,6-Octanedione)Europium 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕
CAS 17631-68-4 MFCD00064655
化学结构图
SMILES: CC(C)(C)/C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)O[Eu](O/C(=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O/C(=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C
化学属性
| Mol. Formula | C30H30EuF21O6 |
|---|---|
| Mol. Weight | 1037 |
| Melting Point | 203-207 °C |
| TSCA | Yes |
别名和识别编码
| Chemical Name | Tris(1,1,1,2,2,3,3-Heptafluoro-7,7-Dimethyl-4,6-Octanedione)Europium |
|---|---|
| MDL Number | MFCD00064655 |
| Synonym | Eu(fod)3 Sievers 试剂 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕(III) 三(6,6,7,7,8,8,8-七氟-2,2-二甲基-3,5-辛二酮酸)铕 Resolve-Al™ EuFOD Siever's reagent |
| EC Number | 241-616-1 |
| CAS Number | 17631-68-4 |
| PubChem Substance ID | 24849895 |
| Chemical Name Translation | 三(1,1,1,2,2,3,3-七氟-7,7-二甲基-4,6-辛二酮酸)铕 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Erbium, NMR - Buffers and Reagents, NMR Solvents and Reagents, Stable Isotopes
相关文献及参考
- NMR shift reagent.
- Mild Lewis acid catalyst for the cycloaddition of heterodienophiles, such as the aldehyde carbonyl group, to oxygen-functionalized dienes e.g. Danishefsky's diene (1-Methoxy-3-trimethylsiloxy-1,3-butadiene, L06100): J. Am. Chem. Soc., 105, 3716 (1983), or 1-methoxybutadiene: Synthesis, 928 (1985). For cycloaddition to lactams, see: J. Org. Chem., 60, 7724 (1995):
- No reaction occurred with lactones or acyclic amides.
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