2-Thienyllithium 2-噻吩基锂
CAS 2786-07-4 MFCD00074987
化学结构图
SMILES: [Li+].[c-]1cccs1
化学属性
| Mol. Formula | C4H3LiS |
|---|---|
| Mol. Weight | 90.07 |
| Density | 0.829 g/mL at 25 °C |
别名和识别编码
| Chemical Name | 2-Thienyllithium |
|---|---|
| MDL Number | MFCD00074987 |
| CAS Number | 2786-07-4 |
| PubChem Substance ID | 76028 |
| Synonym | 2-噻吩基锂 溶液 |
| Chemical Name Translation | 2-噻吩基锂 |
| InChIKey | LNMZIBGBEOKNEI-UHFFFAOYSA-N |
| InChI | InChI=1S/C4H3S.Li/c1-2-4-5-3-1;/h1-3H;/q-1;+1 |
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分类
- {SNA} Chemical Synthesis, Organolithium, Organometallic Reagents, Other Organolithium Reagents
- {SNA} Chemical Synthesis, Organolithium, Organometallic Reagents, Others
安全信息
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- P403+P235
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H332 Harmful if inhaled 吸入有害
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H351 Suspected of causing cancer 怀疑致癌
- H302+H332
GHS Symbol
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R11 Highly flammable 非常易燃
- R48/20
- R14 Reacts violently with water 遇水会猛烈反应
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R51/53
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
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