Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 二(1,5-环辛二烯)四氟硼酸铑(I)

CAS 35138-22-8 MFCD00075045

化学结构图

35138-22-8
SMILES: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C1CC=CCCC=C1

化学属性

TSCANo
Density1.422
Melting Point210°C
Mol. FormulaC16H24BF4Rh
Mol. Weight406.07
Appearance red-brown solid
Stabilityair sensitive

别名和识别编码

Chemical NameBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
EC Number250-023-7
Beilstein Registry Number2384789
Synonym [Rh(COD)2]BF4 {LY} [Rh(COD)2]BF4 {} {LY} [Rh(COD)2]BF4 {} {} {LY} [Rh(COD)2]BF4 {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [Rh(COD)2]BF4 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID172088994
Chemical Name Translation二(1,5-环辛二烯)四氟硼酸铑(I)
Reaxys-RN14342367
LabNetwork Molecule IDLN00199990
MDL NumberMFCD00075045
CAS Number35138-22-8
Canonical SMILESC[Rh](C)(C)C.FB(F)F.C1/C=C\CC/C=C\C1.C2=C\CC/C=C\CC/2.[F-]
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium

产品应用

  • 氢化反应。制备阳离子COD-Rh 复合物。

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Risk Statements
  • R11 Highly flammable 非常易燃
Precautionary statements
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P303+P361+P353
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H228 Flammable solid 易燃固体
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes F
Packing GroupII
UN Number 1759
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
Hazard Class8

其他信息

  • 不溶于水。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Potable- & Waste-Water Testing - Analytical Reagents
  4. Kits/Cases - Potable- & Waste-Water Testing
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhenium
  1. Catalysts
  2. Rhodium
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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