(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine (R)-(-)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺

CAS 55700-44-2 MFCD00075286

化学结构图

55700-44-2
SMILES: C[C@H]([C]1[CH][CH][CH][C]1P(c1ccccc1)c1ccccc1)N(C)C.[CH]1[CH][CH][CH][CH]1.[Fe]

化学属性

Mol. FormulaC26H28FeNP
Mol. Weight441.34
Melting Point141-143
TSCANo
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameFerrocene, 1-​[(1R)​-​1-​(dimethylamino)​ethyl]​-​2-​(diphenylphosphino)​-​, (2R)​-
MDL NumberMFCD00075286
PubChem Substance ID87568958
CAS Number55700-44-2
Synonym (R)-(-)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺
Chemical Name Translation(R)-(-)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺
LabNetwork Molecule IDLN01745846
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
  • {SNA} Asymmetric Synthesis, Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Cross-Coupling, Other Chiral Ligands, Phosphine Compounds, Phosphine Ligands

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+P313
  • P301+P312+P330
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Storage condition Air Sensitive
Hazard Codes Xn
Restrict -

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metallocenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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