(-)-Isopinocampheylborane Tmeda Complex (-)-N,N’-双(单异松蒎基硼烷)-N,N,N’,N’-四甲基乙二胺复合物

CAS 67826-92-0 MFCD00077801

化学结构图

67826-92-0
SMILES: B[C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.B[C@H]1C[C@H]2C[C@@H]([C@@H]1C)C2(C)C.CN(C)CCN(C)C

化学属性

Mol. FormulaC26H54B2N2
Mol. Weight416.35
Melting Point139-141 °C(lit.)

别名和识别编码

Chemical Name(-)-Isopinocampheylborane Tmeda Complex
Synonym (-)-N,N′-双(单异松蒎基硼烷)-N,N,N′,N′-四甲基乙二胺 (R)-Alpine-Boramine™ (-)-异松蒎基硼烷-四甲基乙二胺络合物
MDL NumberMFCD00077801
PubChem Substance ID172089097
Chemical Name Translation(-)-N,N’-双(单异松蒎基硼烷)-N,N,N’,N’-四甲基乙二胺复合物
Reaxys-RN14457642
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H228 Flammable solid 易燃固体
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes F,Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
Hazard Class4.1
UN Number 1325
Packing GroupII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Reduction - Chiral Catalysts, Ligands, and Reagents

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