Diisopropyl Phosphite 亚磷酸二异丙酯

CAS 1809-20-7 MFCD00117905

化学结构图

1809-20-7
SMILES: CC(C)O[PH](=O)OC(C)C

化学属性

Mol. FormulaC6H15O3P
Mol. Weight166.16
Density0.990
TSCAYes
Boiling Point195.5°C at 760 mmHg
Refractive index1.4070 to 1.4090
Solubility可溶
Flash Point69°C
Stability对湿度敏感
Appearance 无色液体,沸点 71 ℃ (8 mmHg),密度 0.997 ,折光率 1.4065-1.4085, 闪点 69 ℃

别名和识别编码

Chemical NameDiisopropyl Phosphite
CAS Number1809-20-7
Synonym Diisopropyl phosphonate {LY} Diisopropyl phosphonate {} {LY} Diisopropyl phosphonate {} {} {LY} Diisopropyl phosphonate {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diisopropyl phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00117905
EC Number217-317-7
Reaxys-RN1703675
Beilstein Registry Number1,363
PubChem Substance ID558181
Chemical Name Translation亚磷酸二异丙酯
InChIKeyBLKXLEPPVDUHBY-UHFFFAOYSA-N
Wiswesser Line Notation1Y1&OPHO&OY1&1
LabNetwork Molecule IDLN01294965
InChIInChI=1S/C6H15O3P/c1-5(2)8-10(7)9-6(3)4/h5-7H,1-4H3
Canonical SMILESO=P(OC(C)C)([H])OC(C)C
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分类

  • Miscellaneous Reagents
  • {uni_hamburg} no charge; 1fragment

产品应用

  • Used as antiwear lubricant additive together with triphenyl thiophosphate on T8 steel/Al2O3 ceramics.

相关文献及参考

  • Short: III/38A
  • Jiang, S., et al.: Wear, 268, 777 (2010),
  • Short: EINECS
  • Short: IV/20B
  • Short: IV/16
  • Beilstein:1,363

安全信息

RTECSSZ7660000
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
Hazard Codes Xn
Signal word
Hazard statements
  • H302+H332
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P302+P352+P332+P313+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P304+P340+P312
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P302+P350
  • P337+P313
GHS Symbol
UN Number 3265
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 9600 mg/m3
TOXIC EFFECTS :
   Behavioral

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1590 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 29(11),51,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 5700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ALBRW* Albright & Wilson Inc.  (P.O. Box 26229, Richmond, VA 23260-6229)
   Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 9010 mg/m3
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - changes in structure or function of salivary glands
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 29(11),51,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

其他信息

  • Acros Organics:亚磷酸二异丙酯 Diisopropyl phosphite, 98%(1809-20-7)
  • 亚磷酸二异丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0629 亚磷酸二异丙酯 Diisopropyl Phosphite 500G 2900元 2014/06/02 P0629 亚磷酸二异丙酯 Diisopropyl Phosphite 25G 414元 2010/06/21 115261000 亚磷酸二异丙酯 Diisopropyl phosphite 98% 100 GR 1862元
  • 用途一:用作农药中间体
  • MOL 文件:1809-20-7.mol
  • 图谱信息:亚磷酸二异丙酯(1809-20-7)红外图谱(IR1) 亚磷酸二异丙酯(1809-20-7)核磁图( 1 HNMR) 亚磷酸二异丙酯(1809-20-7)Raman光谱 亚磷酸二异丙酯(1809-20-7)红外图谱(IR2) 亚磷酸二异丙酯(1809-20-7)核磁图( 13 CNMR) 亚磷酸二异丙酯(1809-20-7)质谱(MS)
  • 上游原料:异丙醇 --> 三氯化磷
  • 下游产品:异稻瘟净 --> 亚磷酸酯 --> O,O-二异丙基硫代磷酸铵
  • 用途二:亚磷酸二异丙酯是一种专用的农药中间体,通过合成O,O-二异丙基硫(醇)代磷酸铵,进而制备有机磷杀菌剂异稻瘟净。
  • Alfa Aesar:亚磷酸二异丙酯,98% Diisopropyl phosphite, 98%(1809-20-7)
  • 方法一:其制备方法是由异丙醇直接与三氯化磷反应,即制得亚磷酸二异丙酯。 3(CH 3 ) 2 CHOH+PCl 3 →[(CH 3 ) 2 CHO] 2 POH+2HCl↑+(CH 3 ) 2 CHCl 将异丙醇以215 kg/h、三氯化磷以150 kg/h的速度[配比为3∶1(mol)]连续进料,混合后猛烈反应,产生的氯化氢气体通过真空汞从混料锅迅速排除,生成的粗酯进入降膜式甩盘脱酸器加热,进一步脱酸,以120~130℃的温度离开脱酸器,将其冷却到40℃以下,即得含量为92%~95%的产品,收率95%~98%。
  • 敏感性:Moisture Sensitive
  • MSDS 信息:Diisopropyl phosphite(1809-20-7).msds
  • TCI Shanghai:亚磷酸二异丙酯 Diisopropyl Phosphite,>;97.0%(GC)(1809-20-7)

系列性分类