Dieldrin 狄氏剂

CAS 60-57-1 MFCD00135591

化学结构图

60-57-1
SMILES: ClC1=C(Cl)[C@]2(Cl)[C@@H]3[C@@H]4C[C@H]([C@@H]3[C@@]1(Cl)C2(Cl)Cl)[C@H]1O[C@@H]41

化学属性

Mol. FormulaC12H8Cl6O
Mol. Weight380.91
Melting Point143-144 °C(lit.)
Vapor Density13.2 (vs air)
Flash Point2 °C
Solubility不溶于水，溶于丙酮、苯、四氯化碳。
Density1.0
Stability对湿度敏感

别名和识别编码

Chemical NameDieldrin
CAS Number60-57-1
Synonym Alvit 55 (1aA,2B,2aA,3B,6B,6aA,7B,7aA)-3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-2,7:3,6-dimethanonaphth(2,3-b)oxirene Dieldrin Kombi-Albertan 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-, (1aR,2R,2aS,3S,6R,6aR,7S,7aS)-rel- Insectlack ENT-1 1,2,3,4,10,10-HEXACHLORO-1,4,4A,5,6,7,8,8A-OCTAHYDRO-6,7-EPOXY-1,4:5,8-DIMETH Compo 1,2,3,4,10,10-HEXACHLORO-6,7-EPOXY-1,4,4A,5,6,7,8,8A-OCTAHYDRO-ENDO,EXO-1,4:5,8-DIMETHANONAPHTHALENE ######## 1,4:5,8-Dimethanonaphthalene, 1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-, endo,exo- 1,2,3,4,10,10-六氯-6,7-环氧-1,4,4A,5,6,7,8,8A-八氢-1,4-内-5,8-外二亚甲基萘 {Chemicalb Shelltox Dildrin dieldrin (INN) 2,7:3,6-Dimethanonaphth[2,3- 狄试剂 1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-endo,exo-1,4,5,8-dimethanonaphthalene NCI-C00124 Aldrin epoxide 2,7:3,6-Dimethanonaphth[2,3-b]oxirene, 3,4,5,6,9,9-hexachloro-1a,2,2a,3,6,6a,7,7a-octahydro-,(1aα,2β,2aα,3β,6β,6aα,7β,7aα)- SD 3417 (1R,4S,4aS,5R,6R,7S,8S,8aR)-1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a, ,8a-octahydro,endo,exo- {u 狄氏劑 Hexachloroepoxyoctahydro-endo,exo-dimethanonaphthalene 地尔君 { Dorytox {uni_hambur (1R,4S,4aS,5R,6R,7S,8S,8aR)-1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-1,4:5,8-dimethanonaphthalene ,8a-octahydro-,endo,exo- 1,2,3,4,10,10-六氯-6,7-环氧-1,4,4,5,6,7,8,8-八氢-1,4-桥5,8-二亚甲基萘 Dieldrex HEOD 氧桥氯甲桥萘 DIELDRIN
PubChem Substance ID969491
EC Number200-484-5
Beilstein Registry Number91396
MDL NumberMFCD00135591
Chemical Name Translation狄氏剂
Merck Number3103
InChIInChI=1S/C12H8Cl6O/c13-8-9(14)11(16)5-3-1-2(6-7(3)19-6)4(5)10(8,15)12(11,17)18/h2-7H,1H2/t2-,3+,4+,5-,6-,7+,10+,11-
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分类

  • 2000/60/EC, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Cyclodienes, D, DID - DIN, Environmental Standards, European Community: ISO, DIN and DL 152, Insecticides, Method Specific, Oeko-Tex Standard 100, Pesticides, Pesticides & Metabolites
  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; alicycle; large ring; fused rings; 3ring; 5ring; 6ring; 7ring; 8ring; 9ring; 10ring; 11ring; ether; 1fragment
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science

产品应用

  • 用作杀虫剂。

相关文献及参考

  • Short: III/20b
  • Merck: 14,3103
  • Short: IV/20B
  • Kearns, C.W., et al.: J. Econ. Entomol., 42, 127 (1949),
  • Short: IV/8A
  • Gaines, et al.: Toxicol. Appl. Pharmacol., 14, 515 (1969),
  • Merck: 14,3103 Beilstein: 17,IV,526

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+,N T+,N,Xn,F,T,Xi
Hazard statements
  • H351 Suspected of causing cancer 怀疑致癌
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSIO1750000
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R25 Toxic if swallowed 吞咽有毒
  • R27 Very toxic in contact with skin 与皮肤接触极毒
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R48/25
  • R36 Irritating to eyes 刺激眼睛
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R50/53
  • R38 Irritating to skin 刺激皮肤
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
Storage condition APPROX 4°C 密封保存。 室温储存
UN Number UN 2811 6.1/PG 1
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品

其他信息

  • 生产方法:由艾氏剂经过过氧乙酸或过氧苯甲酸氧化而得。
  • MOL 文件:60-57-1.mol
  • 用途:狄氏剂为接触性杀虫剂，无内吸性，有一定特效，对大数昆虫有强触杀和胃毒的活性。
  • 稳定性:Stable. Breakdown product of aldrin in the environment. Incompatible with acids, active metals and strong oxidizing agents.
  • HazardClass:6.1(a)
  • 不溶于水，溶于丙酮、苯和四氯化碳等有机溶剂，对酸或碱都稳定，能与多数农药、肥料融和。
  • PackingGroup:II
  • RTECS号:IO1750000
  • 外观性质:工业品为褐色固体。
  • 杀虫剂单一组分标准液
  • 蒸气密度:13.2 (vs air)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DID - DIN - D
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Epoxide Monomers - Monomers
  1. Analytical & Chromatography 分析化学与色谱
  2. Environmental Endocrine Disruptors

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