Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 二(1,5-环辛二烯)三氟甲烷磺酸铑

CAS 99326-34-8 MFCD00143752

化学结构图

99326-34-8
SMILES: C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.O=S(=O)([O-])C(F)(F)F.[Rh+]

化学属性

Mol. FormulaC17H24F3O3RhS
Mol. Weight468
Melting Point159 °C (dec. literature value) (lit.)
SolubilitySoluble in chloroform
TSCANo

别名和识别编码

Chemical NameBis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Synonym Bis(1,5-cyclooctadiene)rhodium(I) triflate 双(1,5-环辛二烯)三氟甲磺酸铑(I) Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate Bis(1,5-cyclooctadiene)rhodium triflate
MDL NumberMFCD00143752
CAS Number99326-34-8
PubChem Substance ID5702638
Chemical Name Translation二(1,5-环辛二烯)三氟甲烷磺酸铑
InChIInChI=1S/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/p-1/b2*2-1-,8-7-;;
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive
Hazard Codes Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物

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