(S)-Alpha,Alpha-Diphenylmethylprolinol α,α-二苯基-N-甲基-L-脯氨醇

CAS 110529-22-1 MFCD00145245

化学结构图

110529-22-1
SMILES: CN1CCC[C@H]1C(O)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

TSCANo
Mol. FormulaC18H21NO
Appearance white to pale-yellow pwdr.
Mol. Weight267
Melting Point66-72

别名和识别编码

Chemical Name(S)-Alpha,Alpha-Diphenylmethylprolinol
MDL NumberMFCD00145245
Synonym (S)-,-Diphenyl-N-methyl-2-pyrrolidinemethanol (S)-α,α-Diphenyl-N-methyl-2-pyrrolidinemethanol (S)-α,α-二苯基-N-甲基-2-吡咯烷甲醇 α,α-二苯基-N-甲基-L-脯氨醇 (S)-α,α-二苯基-N-甲基-2-吡咯烷甲醇
Beilstein Registry Number4749387
PubChem Substance ID87571133
Chemical Name Translationα,α-二苯基-N-甲基-L-脯氨醇
Reaxys-RN1535407
CAS Number110529-22-1
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts

产品应用

  • 二烷基锌不对称加成到羰基化合物的反应所用配体

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Storage condition 储存温度2-8℃

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Proline-Based Organocatalysts - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Proline-Based Organocatalysts - Chiral Catalysts, Ligands, and Reagents
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Amino alcohols
  1. Organocatalyst
  2. Nitrogen
  1. Catalysts
  2. Nitrogen

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