Rhodium(III) Trichloride Hydrate 氯化铑(III)水合物

CAS 20765-98-4 MFCD00149839

化学结构图

20765-98-4
SMILES: O.O.O.[Cl-].[Cl-].[Cl-].[Rh+3]

化学属性

Density1.422
TSCAYes
SolubilitySoluble in alcohol, water. Slightly soluble in acetone
Mol. FormulaCl3Rh?xH2O
Mol. Weight209
Appearance dark red pwdr.
Stabilityhygroscopic
Melting Point100
RedoxReduction

别名和识别编码

Chemical NameRhodium(III) Trichloride Hydrate
Synonym Rhodium trichloride hydrate 氯化铑(III) 水合物
PubChem Substance ID24874167
EC Number233-165-4
Beilstein Registry Number2384789
Merck Number14,8188
Chemical Name Translation氯化铑(III)水合物
LabNetwork Molecule IDLN00198289
MDL NumberMFCD00149839
CAS Number20765-98-4
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Rhodium Catalysts, Rhodium Salts, Salts, 材料科学
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Rhodium, Rhodium Salts, Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Rhodium, Rhodium Salts, Salts, 材料
  • {SNA} Catalysis and Inorganic Chemistry,
  • {SNA} Materials Science,

产品应用

  • 肉桂醛的还原反应的催化剂，伴随芳基硼酸的偶联反应。
  • 甲烷转化成乙酸的催化剂。

相关文献及参考

  • Merck:14,8188

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
WGK Germany3
GHS Symbol
Signal word Danger
Hazard statements
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Storage condition 储存温度2-8℃,充氩保存 Hygroscopic
Packing GroupIII
UN Number UN3260

其他信息

  • 易溶于水、盐酸、丙酮、醇和碱溶液，不溶于醚和王水受强热失去结晶水变为不溶物，进而分解为铑和氯气。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Rhodium Salts - Salts
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhenium
  1. Catalysts
  2. Rhodium

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